Synthesis of poly(2,5-benzimidazole) for use as a fuel-cell membrane

被引：97

作者：

Kim, HJ ^{[1
]}

Cho, SY ^{[1
]}

An, SJ ^{[1
]}

Eun, YC ^{[1
]}

Kim, JY ^{[1
]}

Yoon, HK ^{[1
]}

Kweon, HJ ^{[1
]}

Yew, KH ^{[1
]}

机构：

[1] Samsung SDI Corp, Ctr Res & Dev, Energy Lab, Yongin Si 449577, Gyeonggi Do, South Korea

来源：

MACROMOLECULAR RAPID COMMUNICATIONS | 2004年 / 25卷 / 08期

关键词：

fuel-cell membrane; methanesulfonic acid; phosphorus pentoxide; poly(2,5-benzimidazole); doping; proton conductivity;

D O I：

10.1002/marc.200300288

中图分类号：

O63 [高分子化学（高聚物）];

学科分类号：

070305 ; 080501 ; 081704 ;

摘要：

Poly(2,5-benzimidazole) (ABPBI) was synthesized in a novel polymerization medium containing CH3-SO3H and P2O5. 3,4-Diaminobenzoic acid, a monomer for ABPBI, is soluble in the medium and the polymerization was therefore performed in a homogeneous state. it produced polymer fibers, thus simplifying the work-up process. The membrane was cast directly from the polymerization mixture. Proton conductivities of the ABPBI membranes ranged from 0.02 to 0.06 S.cm(-1) above 100 degreesC, without humidification, and the tensile strength of the membrane was approximately 100 MPa.

引用

页码：894 / 897

页数：4

共 23 条

[1] Polymer electrolyte fuel cells based on phosphoric acid-impregnated poly(2,5-benzimidazole) membranes [J].

Asensio, JA ;

Borró, S ;

Gómez-Romero, P .

JOURNAL OF THE ELECTROCHEMICAL SOCIETY, 2004, 151 (02) :A304-A310

[2] Enhanced conductivity in polyanion-containing polybenzimidazoles.: Improved materials for proton-exchange membranes and PEM fuel cells [J].

Asensio, JA ;

Borrós, S ;

Gómez-Romero, P .

ELECTROCHEMISTRY COMMUNICATIONS, 2003, 5 (11) :967-972

[3] Proton-conducting polymers based on benzimidazoles and sulfonated benzimidazoles [J].

Asensio, JA ;

Borrós, S ;

Gómez-Romero, P .

JOURNAL OF POLYMER SCIENCE PART A-POLYMER CHEMISTRY, 2002, 40 (21) :3703-3710

[4] Proton conduction in acid doped polybenzimidazole [J].

Bouchet, R ;

Siebert, E .

SOLID STATE IONICS, 1999, 118 (3-4) :287-299

[5] Miscibility behavior of polybenzimidazole/sulfonated polysulfone blends for use in fuel cell applications [J].

Deimede, V ;

Voyiatzis, GA ;

Kallitsis, JK ;

Qingfeng, L ;

Bjerrum, NJ .

MACROMOLECULES, 2000, 33 (20) :7609-7617

[6] PHOSPHORUS PENTOXIDE-METHANESULFONIC ACID - CONVENIENT ALTERNATIVE TO POLYPHOSPHORIC ACID [J].

EATON, PE ;

CARLSON, GR ;

LEE, JT .

JOURNAL OF ORGANIC CHEMISTRY, 1973, 38 (23) :4071-4073

[7] Synthesis and characterisation of sulfonated polybenzimidazole: A highly conducting proton exchange polymer [J].

Glipa, X ;

ElHaddad, M ;

Jones, DJ ;

Roziere, J .

SOLID STATE IONICS, 1997, 97 (1-4) :323-331

[8] Hybrid organic-inorganic nanocomposite materials for application in solid state electrochemical supercapacitors [J].

Gómez-Romero, P ;

Chojak, M ;

Cuentas-Gallegos, K ;

Asensio, JA ;

Kulesza, PJ ;

Casañ-Pastor, N ;

Lira-Cantú, M .

ELECTROCHEMISTRY COMMUNICATIONS, 2003, 5 (02) :149-153

[9] New polymer electrolytes based on blends of sulfonated polysulfones with polybenzimidazole [J].

Hasiotis, C ;

Deimede, V ;

Kontoyannis, C .

ELECTROCHIMICA ACTA, 2001, 46 (15) :2401-2406

[10] Development and characterization of acid-doped polybenzimidazole/sulfonated polysulfone blend polymer electrolytes for fuel cells [J].

Hasiotis, C ;

Qingfend, L ;

Deimede, V ;

Kallitsis, JK ;

Kontoyannis, CG ;

Bjerrum, NJ .

JOURNAL OF THE ELECTROCHEMICAL SOCIETY, 2001, 148 (05) :A513-A519

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