Photocatalytic hydrogen production from a noble metal free system based on a water soluble porphyrin derivative and a cobaloxime catalyst

被引：85

作者：

Lazarides, Theodore ^{[1
]}

Delor, Milan ^{[2
]}

Sazanovich, Igor V. ^{[2
]}

McCormick, Theresa M. ^{[3
]}

Georgakaki, Irene ^{[1
]}

Charalambidis, Georgios ^{[1
]}

Weinstein, Julia A. ^{[2
]}

Coutsolelos, Athanassios G. ^{[1
]}

机构：

[1] Univ Crete, Dept Chem, Lab Bioinorgan Chem, Iraklion 71003, Crete, Greece

[2] Univ Sheffield, Dept Chem, Sheffield S3 7HF, S Yorkshire, England

[3] Univ Rochester, Dept Chem, Rochester, NY 14627 USA

来源：

CHEMICAL COMMUNICATIONS | 2014年 / 50卷 / 05期

基金：

英国工程与自然科学研究理事会;

关键词：

MOLECULAR CATALYSTS; HOMOGENEOUS SYSTEM; PHOTOGENERATION; GENERATION; REDUCTION;

D O I：

10.1039/c3cc45025b

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

A combination of noble-metal free components, a water soluble porphyrin photosensitizer zinc meso-tetrakis(1-methylpyridinium-4-yl)porphyrin chloride [ZnTMPyP4+]Cl-4 (1) with cobaloxime complex [Co-III(dmgH)(2)(py)Cl] (2) as a catalyst, creates an efficient system for photochemical hydrogen production acting under visible light with 280 TONs. This is the first example of a water soluble porphyrin acting as a photosensitizer for cobaloxime catalysed H-2 production.

引用

页码：521 / 523

页数：3

共 25 条

[1] Splitting Water with Cobalt [J].

Artero, Vincent ;

Chavarot-Kerlidou, Murielle ;

Fontecave, Marc .

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2011, 50 (32) :7238-7266

[2] Combined Experimental-Theoretical Characterization of the Hydrido-Cobaloxime [HCo(dmgH)2(PnBu3)] [J].

Bhattacharjee, Anirban ;

Chavarot-Kerlidou, Murielle ;

Andreiadis, Eugen S. ;

Fontecave, Marc ;

Field, Martin J. ;

Artero, Vincent .

INORGANIC CHEMISTRY, 2012, 51 (13) :7087-7093

[3] VISIBLE LIGHT-INDUCED OXYGEN GENERATION AND CYCLIC WATER CLEAVAGE SENSITIZED BY PORPHYRINS [J].

BORGARELLO, E ;

KALYANASUNDARAM, K ;

OKUNO, Y ;

GRATZEL, M .

HELVETICA CHIMICA ACTA, 1981, 64 (06) :1937-1942

[4] A PULSE-RADIOLYTIC AND PHOTOCHEMICAL STUDY OF THE OXIDATION OF WATER BY ZINC PORPHYRIN PI-RADICAL CATIONS [J].

CHRISTENSEN, PA ;

HARRIMAN, A ;

PORTER, G ;

NETA, P .

JOURNAL OF THE CHEMICAL SOCIETY-FARADAY TRANSACTIONS II, 1984, 80 :1451-1464

[5] Solar Energy Supply and Storage for the Legacy and Non legacy Worlds [J].

Cook, Timothy R. ;

Dogutan, Dilek K. ;

Reece, Steven Y. ;

Surendranath, Yogesh ;

Teets, Thomas S. ;

Nocera, Daniel G. .

CHEMICAL REVIEWS, 2010, 110 (11) :6474-6502

[6] METAL PHTHALOCYANINES AND PORPHYRINS AS PHOTOSENSITIZERS FOR REDUCTION OF WATER TO HYDROGEN [J].

DARWENT, JR ;

DOUGLAS, P ;

HARRIMAN, A ;

PORTER, G ;

RICHOUX, MC .

COORDINATION CHEMISTRY REVIEWS, 1982, 44 (01) :83-126

[7] Mechanism of H2 Evolution from a Photogenerated Hydridocobaloxime [J].

Dempsey, Jillian L. ;

Winkler, Jay R. ;

Gray, Harry B. .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2010, 132 (47) :16774-16776

[8] Kinetics of Electron Transfer Reactions of H2-Evolving Cobalt Diglyoxime Catalysts [J].

Dempsey, Jillian L. ;

Winkler, Jay R. ;

Gray, Harry B. .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2010, 132 (03) :1060-1065

[9] A homogeneous system for the photogeneration of hydrogen from water based on a platinum(II) terpyridyl acetylide chromophore and a molecular cobalt catalyst [J].

Du, Pingwu ;

Knowles, Kathryn ;

Eisenberg, Richard .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2008, 130 (38) :12576-+

[10] Bi- and terpyridyl platinum(II) chloro complexes: Molecular catalysts for the photogeneration of hydrogen from water or simply precursors for colloidal platinum? [J].

Du, Pingwu ;

Schneider, Jacob ;

Fan, Li ;

Zhao, Wei ;

Patel, Upali ;

Castellano, Felix N. ;

Eisenberg, Richard .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2008, 130 (15) :5056-+

← 1 2 3 →