Chiroselective transcription of the sugar structure to Delta- or Lambda-[Co-III(bpy)(3)](3+) using a boronic acid sugar template interaction

被引：32

作者：

Mizuno, T

Takeuchi, M

Hamachi, I

Nakashima, K

Shinkai, S

机构：

[1] KYUSHU UNIV, FAC ENGN, DEPT CHEM SCI & TECHNOL, FUKUOKA 812, JAPAN

[2] FUKUOKA IND TECHNOL CTR, CHEM & TEXT IND RES INST, CHIKUSHINO, FUKUOKA 818, JAPAN

来源：

CHEMICAL COMMUNICATIONS | 1997年 / 18期

关键词：

D O I：

10.1039/a704041e

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

In order to apply boronic acid-saccharide interactions to the chiroselective synthesis of Delta- and Lambda-[Co-III(bpy)(3)](3+) a saccharide-binding ligand, 2,2'-bipyridine-4,4'-diboronic acid (bpyba) is newly synthesized; the enantiomeric excess under the optimum reaction conditions reached 79% ee!

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页码：1793 / 1794

页数：2

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