A facile route to 1-trifluoromethyl-2,3,4,5-tetramethylcyclopentadienyl ruthenium half- and mixed-sandwich compounds

被引：16

作者：

Evju, JK ^{[1
]}

Mann, KR ^{[1
]}

机构：

[1] Univ Minnesota, Dept Chem, Minneapolis, MN 55455 USA

来源：

ORGANOMETALLICS | 2002年 / 21卷 / 05期

关键词：

D O I：

10.1021/om010863g

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

A series of half and mixed-sandwich (Cpdouble dagger = 1-trifluoromethyl-2,3,4,5-tetramethylcyclopentadienide) ruthenium compounds have been synthesized from a new Cpdouble daggerRu synthon, [Cpdouble daggerRu(NCCH3)(3)](PF6). [Cpdouble daggerRu(NCCH3)(3)](PF6) is efficiently generated by photolysis of [Cpdouble daggerRuBz](PF6) in acetonitrile with a quantum yield of approximately 0.34. The methods described here should be useful for the synthesis of other compounds that contain the Cpdouble daggerRu group.

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页码：993 / 996

页数：4

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