Electrochemical behaviour of a Mg-rich primer in the protection of Al alloys

被引:118
作者
Battocchi, D.
Simoes, A. M.
Tallman, D. E.
Bierwagen, G. P.
机构
[1] N Dakota State Univ, Dept Coatings & Polymer Mat, Fargo, ND 58105 USA
[2] IST, Dept Chem Engn, P-1049001 Lisbon, Portugal
[3] N Dakota State Univ, Dept Chem, Fargo, ND 58105 USA
关键词
Mg-rich primer; AA2024; AA7075; EIS; OCP; potentiodynamic polarization; sacrificial protection;
D O I
10.1016/j.corsci.2005.04.008
中图分类号
T [工业技术];
学科分类号
08 ;
摘要
The electrochemical behaviour of Mg-rich primer on Al Alloys, AA2024 and AA7075, has been studied via Electrochemical Impedance Spectroscopy (EIS), Open Circuit Potential (OCP) and potentiodynamic polarization. Results showed that the Mg-rich primer provides sacrificial protection to the Al substrate by a two-stage mechanism. In a first stage, corrosion of aluminium is prevented by cathodic polarization, whereas at a later stage the precipitation of a porous barrier layer of magnesium oxide was observed. (c) 2005 Elsevier Ltd. All rights reserved.
引用
收藏
页码:1292 / 1306
页数:15
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