High performance organic photovoltaic devices using amorphous molecular materials with high charge-carrier drift mobilities

被引：44

作者：

Kageyama, Hiroshi ^{[2
]}

Ohishi, Hitoshi ^{[2
]}

Tanaka, Masatake ^{[2
]}

Ohmori, Yutaka ^{[3
]}

Shirota, Yasuhiko ^{[1
]}

机构：

[1] Fukui Univ Technol, Dept Environm & Biotechnol Frontier Engn, Fukui 9108505, Japan

[2] Osaka Univ, Fac Engn, Dept Appl Chem, Suita, Osaka 5650871, Japan

[3] Osaka Univ, Ctr Adv Sci & Innovat, Suita, Osaka 5650871, Japan

来源：

APPLIED PHYSICS LETTERS | 2009年 / 94卷 / 06期

关键词：

amorphous state; hole mobility; organic compounds; photoelectric devices; photovoltaic effects; SOLAR-CELLS; CONJUGATED SYSTEMS; POLYMER; DONOR; INTERFACES; SEPARATION; EFFICIENCY; BLENDS; DIODES;

D O I：

10.1063/1.3079399

中图分类号：

O59 [应用物理学];

学科分类号：

摘要：

pn-Heterojunction organic photovoltaic devices (OPVs) using amorphous molecular materials with high hole drift mobilities of 10(-2) cm(2) V-1 s(-1), tris[4-(2-thienyl)phenyl]amine and tris[4-(5-phenylthiophen-2-yl)phenyl]amine, as electron donors and fullerene as an electron acceptor were fabricated. In spite of the use of amorphous materials instead of crystalline materials, the devices exhibited high performance with fill factors of 0.62-0.71 and power conversion efficiencies of 1.5%-1.7% under air-mass 1.5 G illumination at an intensity of 100 mW cm(-2).

引用

页数：3

共 40 条

[1] Star-shaped conjugated systems derived from dithiafulvenyl-derivatized triphenylamines as active materials for organic solar cells [J].

Aleveque, Olivier ;

Leriche, Philippe ;

Cocherel, Nicolas ;

Frere, Pierre ;

Cravino, Antonio ;

Roncali, Jean .

SOLAR ENERGY MATERIALS AND SOLAR CELLS, 2008, 92 (09) :1170-1174

[2] Organic field-effect transistors with high mobility based on copper phthalocyanine [J].

Bao, Z ;

Lovinger, AJ ;

Dodabalapur, A .

APPLIED PHYSICS LETTERS, 1996, 69 (20) :3066-3068

[3] Effect of LiF/metal electrodes on the performance of plastic solar cells [J].

Brabec, CJ ;

Shaheen, SE ;

Winder, C ;

Sariciftci, NS ;

Denk, P .

APPLIED PHYSICS LETTERS, 2002, 80 (07) :1288-1290

[4] Application of metal-doped organic layer both as exciton blocker and optical spacer for organic photovoltaic devices [J].

Chan, M. Y. ;

Lai, S. L. ;

Lau, K. M. ;

Lee, C. S. ;

Lee, S. T. .

APPLIED PHYSICS LETTERS, 2006, 89 (16)

[5] Light-emitting organic solar cells based on a 3D conjugated system with internal charge transfer [J].

Cravino, Antonio ;

Leriche, Philippe ;

Aleveque, Olivier ;

Roquet, Sophie ;

Roncali, Jean .

ADVANCED MATERIALS, 2006, 18 (22) :3033-+

[6] Triphenylamine-oligothiophene conjugated systems as organic semiconductors for opto-electronics [J].

Cravino, Antonio ;

Roquet, Sophie ;

Aleveque, Olivier ;

Leriche, Philippe ;

Frere, Pierre ;

Roncali, Jean .

CHEMISTRY OF MATERIALS, 2006, 18 (10) :2584-2590

[7] MOBILITY OF CHARGE-CARRIERS IN VAPOR-PHASE GROWN C-60 SINGLE-CRYSTAL [J].

FRANKEVICH, E ;

MARUYAMA, Y ;

OGATA, H .

CHEMICAL PHYSICS LETTERS, 1993, 214 (01) :39-44

[8] Bulk-heterojunction photovoltaic devices based on donor-acceptor organic small molecule blends [J].

Gebeyehu, D ;

Maennig, B ;

Drechsel, J ;

Leo, K ;

Pfeiffer, M .

SOLAR ENERGY MATERIALS AND SOLAR CELLS, 2003, 79 (01) :81-92

[9] Conjugated polymer-based organic solar cells [J].

Guenes, Serap ;

Neugebauer, Helmut ;

Sariciftci, Niyazi Serdar .

CHEMICAL REVIEWS, 2007, 107 (04) :1324-1338

[10] EFFICIENT PHOTODIODES FROM INTERPENETRATING POLYMER NETWORKS [J].

HALLS, JJM ;

WALSH, CA ;

GREENHAM, NC ;

MARSEGLIA, EA ;

FRIEND, RH ;

MORATTI, SC ;

HOLMES, AB .

NATURE, 1995, 376 (6540) :498-500

← 1 2 3 4 →