Kinetically Controlled Porosity in a Robust Organic Cage Material

被引：133

作者：

Avellaneda, Antonio ^{[1
]}

Valente, Peter ^{[1
]}

Burgun, Alexandre ^{[1
]}

Evans, Jack D. ^{[1
]}

Markwell-Heys, Adrian W. ^{[1
]}

Rankine, Damien ^{[1
]}

Nielsen, David J. ^{[2
]}

Hill, Matthew R. ^{[3
]}

Sumby, Christopher J. ^{[1
]}

Doonan, Christian J. ^{[1
]}

机构：

[1] Univ Adelaide, Sch Chem & Phys, Adelaide, SA 5005, Australia

[2] Def Sci & Technol Org, Human Protect & Performance Div, Fishermans Bend, Vic 3207, Australia

[3] CSIRO, Mat Sci & Engn, Clayton, Vic 3169, Australia

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2013年 / 52卷 / 13期

基金：

澳大利亚研究理事会;

关键词：

cage compounds; crystallization landscapes; kinetic control; polymorphism; porosity; HIGH SURFACE-AREAS; POROUS MATERIALS; MOLECULAR CAGE; BOND FORMATION; FRAMEWORKS; CRYSTALLINE; DESIGN;

D O I：

10.1002/anie.201209922

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Won by the hare: A new crystalline microporous solid was prepared that is composed of discrete organic cages made entirely from carbon-carbon bonds. The porosity of this material can be controlled by simple kinetic methods, which afford reproducible access to either a non-porous or porous polymorph. Copyright © 2013 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

引用

页码：3746 / 3749

页数：4

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