1:2 Complexes of chloranilic acid with pyrimidine and pyrazine

被引:40
作者
Ishida, H [1 ]
Kashino, S [1 ]
机构
[1] Okayama Univ, Fac Sci, Dept Chem, Okayama 7008530, Japan
关键词
D O I
10.1107/S010827019900709X
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
The hydrogen-bonded 1:2 complexes of chloranilic acid (2,5-dichloro-3,6-dihydroxy-p-benzoquinone) with pyrimidine [(1), C6H2Cl2O4. 2C(4)H(4)N(2)] and pyrazine [(2), C6H2Cl2O4. 2C(4)H(4)N(2)] were prepared and their crystal structures determined at room temperature. In both complexes, the chloranilic acid molecules lie on inversion centres and in each complex, the two components are held together by O-H ... N hydrogen bonds with shore O ... N distances of 2.615 (2) Angstrom for (1) and 2.590 (4) Angstrom for (2).
引用
收藏
页码:1714 / 1717
页数:4
相关论文
共 10 条