Engineering coordination architecture by hydrothermal synthesis; Preparation, X-ray crystal structure and magnetic behaviour of the coordination solid [Mn-3{C6H3(CO2)(3)-1,3,5}(2)]

被引:136
作者
Gutschke, SOH
Molinier, M
Powell, AK
Winpenny, REP
Wood, PT
机构
[1] UNIV E ANGLIA,SCH CHEM SCI,NORWICH NR4 7TJ,NORFOLK,ENGLAND
[2] UNIV EDINBURGH,DEPT CHEM,EDINBURGH EH9 3JJ,MIDLOTHIAN,SCOTLAND
关键词
D O I
10.1039/cc9960000823
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
The hydrothermal reaction of manganese dichloride with the potassium salt of benzene-1,3,5-tricarboxylic acid at 220 degrees C gives [Mn-3{C6H3(CO2)(3)-1,3,5}(2)] which exhibits two pathways for antiferromagnetic coupling.
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页码:823 / 824
页数:2
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