Measurements of thermal conductivity of aqueous LiCl and LiBr solutions from 293 to 473 K at pressures up to 100 MPa

被引:15
作者
Abdulagatov, IM
Magomedov, UB
机构
[1] Institute for Geothermal Problems, Dagestan Scientific Center, Russian Academy of Sciences, Kalinina 39 A, Dagestan
来源
BERICHTE DER BUNSEN-GESELLSCHAFT-PHYSICAL CHEMISTRY CHEMICAL PHYSICS | 1997年 / 101卷 / 04期
关键词
heat conduction; high pressure; transport properties;
D O I
10.1002/bbpc.19971010411
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
High-pressure thermal conductivities of H2O+LiCl and H2O+LiBr have been measured with a parallel-plate apparatus. Data cover the pressure range from 0.1 to 100 MPa at temperatures from 293 to 473 K. The concentrations studied were 0.025, 0.05, 0.10. 0.15, 0.20, and 0.25 mass fraction of salts. The estimated accuracy of the method is about +/-1.6%. The pressure, temperature, and concentration dependence of the thermal conductivity has been studied. Measurements were made on six isobars, namely: 0.1, 20, 40, 60, 80, 100 MPa. The thermal conductivity shows a linear dependence on pressure and concentration at all isotherms. Along each isobar a given concentration shows the thermal-conductivity maximum at temperatures about 413 K. The measured values of thermal conductivity are compared with the results of other investigators.
引用
收藏
页码:708 / 711
页数:4
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