Novel columnar mesogen with octupolar optical nonlinearities: synthesis, mesogenic behavior and multiphoton-fluorescence-free hyperpolarizabilities of subphthalocyanines with long aliphatic chains

被引：73

作者：

Kang, SH

Kang, YS

Zin, WC

Olbrechts, G

Wostyn, K

Clays, K

Persoons, A

Kim, K

机构：

[1] Univ Louvain, Dept Chem, Ctr Res Mol Elect & Photon, Lab Chem & Biol Dynam, B-3001 Louvain, Belgium

[2] Pohang Univ Sci & Technol, Dept Mat Sci & Engn, Pohang 790784, South Korea

[3] Pohang Univ Sci & Technol, Dept Chem, Natl Creat Res Initiat Smart Supramol, Pohang 790784, South Korea

来源：

CHEMICAL COMMUNICATIONS | 1999年 / 17期

关键词：

D O I：

10.1039/a904254g

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Novel subphthalocyanines with long thioalkyl chains exhibit hexagonal columnar mesophases at room temperature; their inherent first hyperpolarizability values (beta) measured by hyper-Rayleigh scattering (HRS) with fluorescence suppression are (189 +/- 30) x 10(-30) esu at 1300 nm.

引用

页码：1661 / 1662

页数：2

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