Functionalized mesoporous hybrid thin films as selective membranes

被引：48

作者：

Otal, EH

Angelomé, PC

Bilmes, SA

Soler-Illia, GJAA

机构：

[1] Univ Buenos Aires, DQIAyQF, RA-1428 Buenos Aires, DF, Argentina

[2] Univ Buenos Aires, INQUIMAE, RA-1428 Buenos Aires, DF, Argentina

[3] CAC, Comis Nacl Energia Atom, Unidad Activ Quim, RA-1650 Buenos Aires, DF, Argentina

来源：

ADVANCED MATERIALS | 2006年 / 18卷 / 07期

关键词：

D O I：

10.1002/adma.200502215

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Mesoporous thin films containing organic functionalities behave like selective membranes. Titania mesoporous films with an accessible cubic mesostructure are deposited on a conductive electrode (see figure). Organic groups (phenyl, hexadecyl, glycerol) are added to the pore surface by post-grafting. The transport properties of electrochemical probes such as ferrocyanide or ferrocenedimethanol within the pore system depend on the grafted functionalities.

引用

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页码：934 / +

页数：6

相关论文

共 49 条

[1] Ordered mesoporous hybrid thin films with double organic functionality and mixed oxide framework [J].

Angelomé, PC ;

Soler-Illia, GJDA .

JOURNAL OF MATERIALS CHEMISTRY, 2005, 15 (35-36) :3903-3912

[2] Hybrid non-silica mesoporous thin films [J].

Angelomé, PC ;

Aldabe-Bilmes, S ;

Calvo, ME ;

Crepaldi, EL ;

Grosso, D ;

Sanchez, C ;

Soler-Illia, GJAA .

NEW JOURNAL OF CHEMISTRY, 2005, 29 (01) :59-63

[3] Organically modified transition-metal oxide mesoporous thin films and xerogels [J].

Angelomé, PC ;

Soler-Illia, GJDAA .

CHEMISTRY OF MATERIALS, 2005, 17 (02) :322-331

[4]

ANGELOME PC, UNPUB TEM AFM IMAGES

[5] New nanocomposites: putting organic function "inside" the channel walls of periodic mesoporous silica [J].

Asefa, T ;

Yoshina-Ishii, C ;

MacLachlan, MJ ;

Ozin, GA .

JOURNAL OF MATERIALS CHEMISTRY, 2000, 10 (08) :1751-1755

[6]

BARD AJ, 1980, ELECTROCHEMICAL METH

[7] A general one-pot process leading to highly functionalised ordered mesoporous silica films [J].

Cagnol, F ;

Grosso, D ;

Sanchez, C .

CHEMICAL COMMUNICATIONS, 2004, (15) :1742-1743

[8] Conjugated polymer photovoltaic cells [J].

Coakley, KM ;

McGehee, MD .

CHEMISTRY OF MATERIALS, 2004, 16 (23) :4533-4542

[9] Infiltrating semiconducting polymers into self-assembled mesoporous titania films for photovoltaic applications [J].

Coakley, KM ;

Liu, YX ;

McGehee, MD ;

Frindell, KL ;

Stucky, GD .

ADVANCED FUNCTIONAL MATERIALS, 2003, 13 (04) :301-306

[10] Controlled formation of highly organized mesoporous titania thin films:: From mesostructured hybrids to mesoporous nanoanatase TiO2 [J].

Crepaldi, EL ;

Soler-Illia, GJDA ;

Grosso, D ;

Cagnol, F ;

Ribot, F ;

Sanchez, C .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2003, 125 (32) :9770-9786

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