1,1′,2,2′-tetrakis(diphenylphosphino)-4,4′-di-tert-butylferrocene, a new cisoid arrangement of phosphino groups

被引：17

作者：

Broussier, R

Bentabet, E

Amardeil, R

Richard, P

Meunier, P

Kalck, P

Gautheron, B

机构：

[1] Univ Bourgogne 1, UMR 5632, Lab Synthese & Electrosynthese Organomet, F-21000 Dijon, France

[2] Ecole Natl Super Chim, Lab Catalyse Chim Fine & Polymeres, F-31077 Toulouse, France

来源：

JOURNAL OF ORGANOMETALLIC CHEMISTRY | 2001年 / 637卷

关键词：

phosphinoferrocene; Group IX and X complexes; cisoid; arrangement;

D O I：

10.1016/S0022-328X(01)00883-X

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The action of two equivalents of 1,2-bis(diphenylphosphino)-4-tert-butylcyclopentadienyllithium on FeCl2 led to the corresponding 1,1',2,2'-tetraphosphinoferrocene. The X-ray structure of this bulky ferrocene is described. The spectroscopic results reveal a conformational chirality with a cisoid disposition of the phosphino groups. The first results about the complexation with representative elements of Group IX and X (Rh, Pd, Ir) are reported. (C) 2001 Elsevier Science B.V. All rights reserved.

引用

页码：126 / 133

页数：8

共 40 条

[1] [Anonymous], 1998, SHELX 97 INCLUDES SH
[2] ANTBERG M, 1986, ACTA CRYSTALLOGR C, V42, P997, DOI 10.1107/S0108270186093733
[3] LINEAR OLIGOPHOSPHAALKANES .4. SYNTHESIS AND STRUCTURE OF NICKEL(II) COMPLEXES OF CHIRAL TETRAPHOSPHAALKANES RR'P-[CH2]3-PME-[CH2]M-PME-[CH2]3-PRR' (R=ME-R'=H,ME,M=2,3)
BAACKE, M
HIETKAMP, S
MORTON, S
STELZER, O
[J]. CHEMISCHE BERICHTE-RECUEIL, 1982, 115 (04): : 1389 - 1398
[4] LOW-TEMPERATURE CRYSTAL-STRUCTURE OF A 5-COORDINATE IRON(II) COMPLEX EXHIBITING SINGLET TRIPLET SPIN EQUILIBRIUM
BACCI, M
GHILARDI, CA
ORLANDINI, A
[J]. INORGANIC CHEMISTRY, 1984, 23 (18) : 2798 - 2802
[5] CLASSICAL, NONCLASSICAL, AND MIXED-METAL OSMIUM(II) POLYHYDRIDES STABILIZED BY THE TETRAPHOSPHINE P(CH2CH2PPH2)3 - H/D ISOTOPE-EXCHANGE REACTIONS PROMOTED BY A STRONGLY BOUND DIHYDROGEN LIGAND
BIANCHINI, C
LINN, K
MASI, D
PERUZZINI, M
POLO, A
VACCA, A
ZANOBINI, F
[J]. INORGANIC CHEMISTRY, 1993, 32 (11) : 2366 - 2376
[6] EVIDENCE FOR A MOLECULAR-HYDROGEN COMPLEX OF RHODIUM - SOME FACTORS AFFECTING CIS-DIHYDRIDE REVERSIBLE ETA-2-DIHYDROGEN EXCHANGE
BIANCHINI, C
MEALLI, C
PERUZZINI, M
ZANOBINI, F
[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1987, 109 (18) : 5548 - 5549
[7] A STABLE ETA-2-H-2 COMPLEX OF COBALT - ROLE OF THE H-H INTERACTION IN HYDROGEN TRANSFER FROM METAL TO ALKENE
BIANCHINI, C
MEALLI, C
MELI, A
PERUZZINI, M
ZANOBINI, F
[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1988, 110 (26) : 8725 - 8726
[8] METAL HYDRIDE ALKYNYL -] METAL VINYLIDENE REARRANGEMENTS OCCURRING IN BOTH SOLID-STATE AND SOLUTION - ROLE OF THE 1-ALKYNE SUBSTITUENT IN DETERMINING THE RELATIVE STABILITY OF PI-ALKYNE, HYDRIDE ALKYNYL, AND VINYLIDENE FORMS AT COBALT
BIANCHINI, C
PERUZZINI, M
VACCA, A
ZANOBINI, F
[J]. ORGANOMETALLICS, 1991, 10 (10) : 3697 - 3707
[9] REGIOSELECTIVE AND STEREOSELECTIVE DIMERIZATION OF PHENYLACETYLENE TO (Z)-1,4-DIPHENYLBUT-3-EN-1-YNE BY RUTHENIUM(II) CATALYSIS - REACTION-MECHANISM INVOLVING INTERMOLECULAR PROTONATION OF SIGMA-ALKYNYL BY 1-ALKYNE
BIANCHINI, C
FREDIANI, P
MASI, D
PERUZZINI, M
ZANOBINI, F
[J]. ORGANOMETALLICS, 1994, 13 (11) : 4616 - 4632
[10] A RU(II) ENYNYL COMPLEX MEDIATES THE CATALYTIC DIMERIZATION OF 1-ALKYNES TO Z-1,4-DISUBSTITUTED ENYNES
BIANCHINI, C
PERUZZINI, M
ZANOBINI, F
FREDIANI, P
ALBINATI, A
[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1991, 113 (14) : 5453 - 5454

← 1 2 3 4 →