Three-dimensional hydrodynamic lattice-gas simulations of ternary amphiphilic fluids under shear flow

被引:6
作者
Love, PJ [1 ]
Coveney, PV [1 ]
机构
[1] Univ London Queen Mary, Ctr Computat Sci, London E1 4NS, England
来源
PHILOSOPHICAL TRANSACTIONS OF THE ROYAL SOCIETY A-MATHEMATICAL PHYSICAL AND ENGINEERING SCIENCES | 2002年 / 360卷 / 1792期
关键词
lattice gas; surfactants; shear flow; microemulsions;
D O I
10.1098/rsta.2001.0949
中图分类号
O [数理科学和化学]; P [天文学、地球科学]; Q [生物科学]; N [自然科学总论];
学科分类号
07 ; 0710 ; 09 ;
摘要
We describe the implementation of shear flow in a three-dimensional lattice-gas model for amphiphilic fluids. We investigate the effect of shear on the morphology of the bicontinuous ternary microemulsion phase., and in particular its effect on the formation and stability of a lamellar phase. Metastable lamellar phases were observed for both 32(3) and 64(3) systems subjected to shear, and the stability of preformed lamellar phases under shear flow established for both 64(3) and 128(3) systems. The effect of micellization on interfacial behaviour in these phases is discussed in the context of the linear non-equilibrium thermodynamic theory of rate processes and nonlinear Becker-Doring aggregation theory.
引用
收藏
页码:357 / 366
页数:10
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