Synthesis of fluorine-containing block copolymers via ATRP 2. Synthesis and characterization of semifluorinated di- and triblock copolymers

被引：68

作者：

Zhang, ZB ^{[1
]}

Ying, SK

Shi, ZQ

机构：

[1] E China Univ Sci & Technol, Lab Living Polymerizat, Shanghai 200237, Peoples R China

[2] Shanghai Inst Organo Fluorine Mat, Shanghai, Peoples R China

来源：

POLYMER | 1999年 / 40卷 / 19期

关键词：

atom transfer radical polymerization; semifluorinated block copolymer;

D O I：

10.1016/S0032-3861(99)00029-4

中图分类号：

O63 [高分子化学（高聚物）];

学科分类号：

070305 ; 080501 ; 081704 ;

摘要：

A series of semifluorinated fluorocarbon/hydrocarbon di- and triblock copolymers were prepared by atom transfer radical polymerization (ATRP). The mono- and difunctional macroinitiators, which were obtained from bulk ATRP of styrene, butyl acrylate and methyl acrylate, initiated solution ATRP of 2- [(perfluorononenyl)oxy]ethyl methacrylate and ethylene glycol mono-methacrylate mono-perfluorooctanoate, respectively. The formation of the block copolymer was confirmed with size exclusion chromatography and H-1 NMR spectrum. (C) 1999 Published by Elsevier Science Ltd. All rights reserved.

引用

页码：5439 / 5444

页数：6

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