Hydrogen production from organic material reaction with supercritical water accompanied by CO2 adsorption

被引:19
作者
Lin, SY [1 ]
Suzuki, Y
Hatano, H
Harada, M
机构
[1] Natl Inst Resources & Environm, Thermal Energy & Combust Engn Dept, Tsukuba, Ibaraki 3058569, Japan
[2] New Energy & Ind Technol Dev Org, Tokyo, Japan
[3] Ctr Coal Utilizat, Tokyo, Japan
关键词
hydeogen; energy; environment; coal; waste; supercritical water;
D O I
10.1252/kakoronbunshu.25.498
中图分类号
TQ [化学工业];
学科分类号
0817 ;
摘要
Hydrogen productivity from the reactions of organic material(s) with supercritical water was investigated in range of pressure 23-105 MPa and temperature of 923 K by using a micro-autoclave. CO2 was absorbed by a sorbent during the reactions in the micro-autoclave. It was found that about 170 cm(3) gas with 80% H-2 and 20% CH4 was produced from 0.1 g Taiheiyo coal at 60 MPa and 923 K. At this case, about 90% carbon in the Taiheiyo coal was converted to produce I-Is. Some materials included chlorine and sulfur, such as the Polyvinyl chloride and the Sludge also produced gases which mainly contained H-2 and CH4, no chlorine and sulfur gases can be found in these products.
引用
收藏
页码:498 / 500
页数:3
相关论文
共 2 条
[1]  
JOHNSON JL, 1979, KINETICS COAL GASIFI
[2]  
KAGIYA Z, 1969, KAGAKU HANNO NO SOKU