Crystallographic characterization and structural analysis of the first organic functionalization product of the endohedral fullerene SC3N@C80

被引：121

作者：

Lee, HM ^{[1
]}

Olmstead, MM ^{[1
]}

Iezzi, E ^{[1
]}

Duchamp, JC ^{[1
]}

Dorn, HC ^{[1
]}

Balch, AL ^{[1
]}

机构：

[1] Univ Calif Davis, Dept Chem, Davis, CA 95616 USA

来源：

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY | 2002年 / 124卷 / 14期

关键词：

D O I：

10.1021/ja020065x

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The structure of Sc3N@C80-C10H12O2, a Diels-Alder cycloadduct of Sc3N@C80, has been determined. The crystallographic data shows that cycloaddition occurs at a C-C bond of 6:5 ring junction, and that the fullerene C1-C2 bond is elongated and pulled out from the fullerene. The Sc3N unit is well-ordered within the C80 cage and positioned away from the site of addition. The proximity of the Sc atoms to the cage carbon atoms causes those carbon atoms to protrude slightly from the surface of the fullerene cage. Copyright © 2002 American Chemical Society.

引用

页码：3494 / 3495

页数：2

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