On the chemistry of gold in silicate glasses:: Studies on a nonthermally activated growth of gold nanoparticles

被引:27
作者
Eichelbaum, M
Rademann, K
Müller, R
Radtke, M
Riesemeier, H
Görner, W
机构
[1] Humboldt Univ, Inst Chem, D-12489 Berlin, Germany
[2] Bundesanstalt Mat Forsch & Prufung, BAM, D-12205 Berlin, Germany
关键词
glasses; gold; nanostructures; surface plasmon resonance; X-ray absorption spectroscopy;
D O I
10.1002/anie.200502174
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
(Figure Presented) Gold in glass: Activating gold silicate glasses with synchrotron X-rays results in the spatial reduction of cationic gold to gold atoms. Subsequent annealing allows the growth of nanoparticles with defined sizes and tailored optical properties (see picture). This opens up new vistas in functionalizing chemically and mechanically stable glasses for integrated nanophotonic applications. © 2005 Wiley-VCH Verlag GmbH & Co. KGaA.
引用
收藏
页码:7905 / 7909
页数:5
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