Crystal structure of kinetic and thermodynamic coordination networks formed between 3,3′-dipyridylethyne and copper bromide

被引：23

作者：

Bosch, E ^{[1
]}

Barnes, CL

机构：

[1] SW Missouri State Univ, Dept Chem, Springfield, MO 65804 USA

[2] Univ Missouri, Dept Chem, Columbia, MO 65211 USA

来源：

NEW JOURNAL OF CHEMISTRY | 2001年 / 25卷 / 11期

关键词：

D O I：

10.1039/b106221m

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Reaction of copper(I) bromide with 3,3'-dipyridylethyne yielded rhomboid yellow crystals that are stable when removed from the mother liquor. X-Ray crystallographic analysis identified the one-dimensional coordination polymer formed with pairs of dipyridyl ligands bridging rhombic units. The crystals CuBr2Cu left in the mother liquor re-dissolved and formed orange hexagonal prisms that were shown to be a stable three-dimensional network comprising interwoven ligand-copper ribbons linked together by infinite copper-bromide chains.

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页码：1376 / 1378

页数：3

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