Synthesis and structures of neutral and cationic 1-azaallyl-aluminium methyls

被引：12

作者：

Bourget, L ^{[1
]}

Hitchcock, PB ^{[1
]}

Lappert, MF ^{[1
]}

机构：

[1] Univ Sussex, Chem Lab, Brighton BN1 9QJ, E Sussex, England

来源：

JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS | 1999年 / 16期

关键词：

D O I：

10.1039/a904138i

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The 1-azaallylaluminium compounds [Al{N( R)C(Bu-t)C(H) R}{N(R)C(Bu-t)=C(H)R}Me] (X-ray characterised), Al{N(R)C(Bu-t)C(H)R}Me-2, Al{N(R)C(Ph)=C(H)R}Me-2 3 and Al{N(R)C(Ph)=C(H)R}(2)Me(thf) were obtained from the appropriate methylaluminium chloride and 1-azaallyllithium; 3 with B(C6F5)(3) gave [Al{N(R)C(Ph)=C(H)R}Me(thf)(OEt2)][BMe(C6F5)(3)] (R = SiMe3).

引用

页码：2645 / 2646

页数：2

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