Electrochemical and photophysical properties of a novel polythiophene with pendant fulleropyrrolidine moieties: Toward "double cable" polymers for optoelectronic devices

被引:83
作者
Cravino, A [1 ]
Zerza, G
Neugebauer, H
Maggini, M
Bucella, S
Menna, E
Svensson, M
Andersson, MR
Brabec, CJ
Sariciftci, NS
机构
[1] Johannes Kepler Univ Linz, Linz Inst Organ Solar Cells, LIOS, A-4040 Linz, Austria
[2] Univ Padua, Dept Organ Chem, CNR, CMRO, I-35131 Padua, Italy
[3] Chalmers Univ Technol, SE-41296 Gothenburg, Sweden
关键词
D O I
10.1021/jp013077y
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
We have prepared a novel bithiophene carrying a fulleropyrrolidine substituent. Its electrochemical polymerization affords an electron donor-acceptor material that has been studied by means of electrochemical and spectroscopic techniques. The results from photoinduced absorption (PIA) and light-induced electron spin resonance (LESR) experiments demonstrate a photoinduced electron transfer from the polythiophene backbone to the tethered acceptor moieties.
引用
收藏
页码:70 / 76
页数:7
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