Complexation with barium(II) allows the inference of the absolute configuration of primary amines by NMR

被引：50

作者：

López, B

Quiñoá, E

Riguera, R ^{[1
]}

机构：

[1] Univ Santiago de Compostela, Fac Quim, Dept Quim Organ, E-15706 Santiago, Spain

[2] Univ Santiago de Compostela, Inst Acuicultura, E-15706 Santiago, Spain

来源：

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY | 1999年 / 121卷 / 41期

关键词：

D O I：

10.1021/ja990597m

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

引用

页码：9724 / 9725

页数：2

共 14 条

[1]

García-Martínez C, 1998, MAGN RESON CHEM, V36, P429, DOI 10.1002/(SICI)1097-458X(199806)36:6<429::AID-OMR306>3.0.CO

[2]

2-T

[3] Applications of MTPA (Mosher) amides of secondary amines: Assignment of absolute configuration in chiral cyclic amines [J].

Hoye, TR ;

Renner, MK .

JOURNAL OF ORGANIC CHEMISTRY, 1996, 61 (24) :8489-8495

[4] CONFORMATIONAL STRUCTURE AND DYNAMICS OF ARYLMETHOXYACETATES - DNMR SPECTROSCOPY AND AROMATIC SHIELDING EFFECT [J].

LATYPOV, SK ;

SECO, JM ;

QUINOA, E ;

RIGUERA, R .

JOURNAL OF ORGANIC CHEMISTRY, 1995, 60 (03) :504-515

[5] MTPA vs MPA in the determination of the absolute configuration of chiral alcohols by H-1 NMR [J].

Latypov, SK ;

Seco, JM ;

Quinoa, E ;

Riguera, R .

JOURNAL OF ORGANIC CHEMISTRY, 1996, 61 (24) :8569-8577

[6] DETERMINATION OF THE ABSOLUTE STEREOCHEMISTRY OF CHIRAL AMINES BY H-1-NMR OF ARYLMETHOXYACETIC ACID-AMIDES - THE CONFORMATIONAL MODEL [J].

LATYPOV, SK ;

SECO, JM ;

QUINOA, E ;

RIGUERA, R .

JOURNAL OF ORGANIC CHEMISTRY, 1995, 60 (06) :1538-1545

[7] Are both the (R)- and the (S)-MPA esters really needed for the assignment of the absolute configuration of secondary alcohols by NMR?: The use of a single derivative [J].

Latypov, SK ;

Seco, JM ;

Quiñoá, E ;

Riguera, R .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1998, 120 (05) :877-882

[8] Determining factors in the assignment of the absolute configuration of alcohols by NMR. The use of anisotropic effects on remote positions. [J].

Seco, JM ;

Latypov, SK ;

Quinoa, E ;

Riguera, R .

TETRAHEDRON, 1997, 53 (25) :8541-8564

[9] Boc-phenylglycine:: The reagent of choice for the assignment of. The absolute configuration of α-chiral primary amines by 1H NMR spectroscopy [J].

Seco, JM ;

Quiñoá, E ;

Riguera, R .

JOURNAL OF ORGANIC CHEMISTRY, 1999, 64 (13) :4669-4675

[10] Choosing the right reagent for the determination of the absolute configuration of amines by NMR: MTPA or MPA? [J].

Seco, JM ;

Latypov, SK ;

Quinoa, E ;

Riguera, R .

JOURNAL OF ORGANIC CHEMISTRY, 1997, 62 (22) :7569-7574

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