Diplatinum(III) tetrakis(beta-diketonato) complexes exemplifying the unsupported Pt-Pt bond

被引：14

作者：

Prenzler, PD ^{[1
]}

Heath, GA ^{[1
]}

Lee, SB ^{[1
]}

Raptis, RG ^{[1
]}

机构：

[1] AUSTRALIAN NATL UNIV,CANBERRA,ACT 0200,AUSTRALIA

来源：

CHEMICAL COMMUNICATIONS | 1996年 / 19期

关键词：

D O I：

10.1039/cc9960002271

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Coupling of tervalent ClPt(acac)(2) moieties to form diamagnetic, directly Pt-Pt bonded [Pt2Cl2(acac)(4)] occurs in the course of oxidative addition of Cl-2 to [Pt(acac)(2)] [acac = R(CO)CH(CO)R' and R/R' = Me/Me, Me/CF3 or Ph/Ph].

引用

页码：2271 / 2272

页数：2

共 13 条

[1] NMR-SPECTRA OF PLATINUM(III) COMPLEXES WITH SULFATO-BRIDGES AND PHOSPHATO-BRIDGES [J].

APPLETON, TG ;

HALL, JR ;

NEALE, DW .

INORGANICA CHIMICA ACTA-ARTICLES AND LETTERS, 1985, 104 (01) :19-31

[2] THE STEREOCHEMISTRY OF COMPLEX INORGANIC COMPOUNDS .10. THE STEREOISOMERS OF DICHLOROBIS-(ETHYLENEDIAMINE)-PLATINUM (IV) CHLORIDE [J].

BASOLO, F ;

BAILAR, JC ;

TARR, BR .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1950, 72 (06) :2433-2438

[3] SYNTHESIS AND CHARACTERIZATION OF A DIPLATINUM(III)-TETRAKIS(ALPHA-DIOXIMATO) COMPLEX CONTAINING AN UNSUPPORTED METAL METAL BOND [J].

BAXTER, LAM ;

HEATH, GA ;

RAPTIS, RG ;

WILLIS, AC .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1992, 114 (17) :6944-6946

[4] SYNTHESIS AND X-RAY STRUCTURAL CHARACTERIZATION OF THE 1ST UNBRIDGED DIPLATINUM(III) COMPOUND - BIS[BIS(1-IMINO-1-HYDROXY-2,2-DIMETHYLPROPANE)TRI-CHLOROPLATINUM(III)] [J].

CINI, R ;

FANIZZI, FP ;

INTINI, FP ;

NATILE, G .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1991, 113 (20) :7805-7806

[5]

DIKAREVA LM, 1989, ZH NEORG KHIM+, V34, P391

[6] FROM (RUX6) TO (RU(RCN)6) - SYNTHESIS OF MIXED HALIDE NITRILE COMPLEXES OF RUTHENIUM, AND THEIR SPECTROELECTROCHEMICAL CHARACTERIZATION IN MULTIPLE OXIDATION-STATES [J].

DUFF, CM ;

HEATH, GA .

JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 1991, (09) :2401-2411

[7] PREPARATION AND VIBRATIONAL-SPECTRA OF TRANS-[PT(ACAC)2CL2], TRANS-[PT(ACAC)2BR2], TRANS-[PT(ACAC)2I2], TRANS-[PT(ACAC)2SCN2], TRANS-[PT(ACAC)2SECN2], TRANS-[PT(ACAC)2N-3(2)] [J].

GRABOWSKI, A ;

PREETZ, W .

ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE, 1987, 544 (01) :95-100

[8] REDOX-ACTIVE PLANAR COMPLEXES - ELECTROCHEMICAL INVESTIGATIONS OF PALLADIUM AND PLATINUM BIS(DITHIOACETYLACETONATE) COMPLEXES AND THEIR STRUCTURAL ANALOGS [J].

HEATH, GA ;

LESLIE, JH .

JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 1983, (08) :1587-1592

[9]

HEATH GA, UNPUB

[10] CIS- AND TRANS-TETRACHLORODIAMMINEPLATINUM(IV) [J].

KAUFFMAN, GB .

INORGANIC SYNTHESES, 1963, 7 :236-238

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