Soft (S3-donor) scorpionate complexes of molybdenum and tungsten carbonyls

被引：48

作者：

Garner, M ^{[1
]}

Lehmann, MA ^{[1
]}

Reglinski, J ^{[1
]}

Spicer, MD ^{[1
]}

机构：

[1] Univ Strathclyde, Dept Pure & Appl Chem, Glasgow G1 1XL, Lanark, Scotland

来源：

ORGANOMETALLICS | 2001年 / 20卷 / 24期

关键词：

D O I：

10.1021/om010559n

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The dicarbonyl(eta (3)-allyl)molybdenum and tri-carbonyliodotungsten complexes with hydrotris(methimazolyl)borate (Tm) are reported as the first examples of transition-metal organometallic complexes of the Tm ligand, serving as general entry points for a wide range of group 6 organometallic complexes. Their crystal structures have been determined, and comparisons are made with the homologous pyrazolylborate (Tp) and cyclopentadienyl (Cp) complexes, leading to predictions regarding their reactions.

引用

页码：5233 / 5236

页数：4

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