On the effect of 1,2-disubstitution with Me(3)M(M=Si, Ge, Sn) groups upon the electronic structure of 3,3-dimethylcyclopropene

被引：15

作者：

EckertMaksic, M

Elbel, S

Stohlmeier, M

Untiedt, S

deMeijere, A

机构：

[1] TECH FACHHSCH BERLIN,FB 3B,D-13353 BERLIN,GERMANY

[2] UNIV GOTTINGEN,INST ORGAN CHEM,D-37077 GOTTINGEN,GERMANY

来源：

CHEMISCHE BERICHTE | 1996年 / 129卷 / 02期

关键词：

electronic structure; cyclopropenes, 3,3-dimethyl-;

D O I：

10.1002/cber.19961290210

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

He(I) PE spectra of a series of 3,3-dimethylcyclopropenes bearing Me(3)Si (1), Me(3)Ge (2), and Me(3)Sn (3) groups in the 1- and 2-positions, as well as the He(II) PE spectra of 1 and 3 were recorded. The changes in the lowest energy ionizations along the series are interpreted in terms of inductive and hyperconjugative interactions. The new compounds were prepared by reaction of lithiated 3,3-dimethylcyclopropene with the corresponding trimethylmetal chlorides.

引用

页码：169 / 174

页数：6

共 59 条

[1]

[Anonymous], 1975, PMO THEORY ORGANIC C

[2] 1-HALOCYCLOPROPENES AND PROPARGYLIC HALIDES FROM THE REACTION OF TRIHALOCYCLOPROPANES WITH METHYL LITHIUM [J].