Vibrational spectroscopic study on pyrimidine metal(II) tetracyanometalate complexes

被引：12

作者：

Bahat, M ^{[1
]}

Yurdakul, S ^{[1
]}

机构：

[1] Gazi Univ, Fen Edebiyat Fakultesi, Fizik Bolumu, TR-06500 Ankara, Turkey

来源：

SPECTROCHIMICA ACTA PART A-MOLECULAR AND BIOMOLECULAR SPECTROSCOPY | 2002年 / 58卷 / 05期

关键词：

Hofmann-type complexes; pyrimidine; IR and Raman spectra; vibrational assignment;

D O I：

10.1016/S1386-1425(01)00562-5

中图分类号：

O433 [光谱学];

学科分类号：

0703 ; 070302 ;

摘要：

The results of an infrared and Raman spectroscopic study are reported for seven new metal(II): pyrimidine tetracyanonickelate complexes, M(pyr)(2)Ni(CN)(4) [where (pyr) == pyrimidine; M = Mn, Fe, Co, Zn, Ni, Cu or Cd] and an IR spectroscopic study is presented for new cadmium pyrimidine tetracyanometalate complex. Cd(pyr)(2)Cd(CTq)(4), The spectral data suggest that the first seven compounds belong to the Hofmann-type and the last compound belongs to the Hofmann-T-d-type of complexes. (C) 2002 Elsevier Science B.V. All rights reserved.

引用

页码：933 / 939

页数：7

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