High-Efficiency Polymer Solar Cells via the Incorporation of an Amino-Functionalized Conjugated Metallopolymer as a Cathode Interlayer

被引:326
作者
Liu, Shengjian [1 ]
Zhang, Kai [1 ]
Lu, Junming [1 ]
Zhang, Jie [1 ]
Yip, Hin-Lap [1 ]
Huang, Fei [1 ]
Cao, Yong [1 ]
机构
[1] S China Univ Technol, State Key Lab Luminescent Mat & Devices, Inst Polymer Optoelect Mat & Devices, Guangzhou 510640, Guangdong, Peoples R China
关键词
PHOTOVOLTAIC CELLS; MORPHOLOGY; DIFFUSION; LAYER; OXIDE; FILM;
D O I
10.1021/ja408363c
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
An amino-functionalized conjugated metallopolymer PFEN-Hg was developed as a cathode interlayer for inverted polymer solar cells. The resulting devices exhibited significantly improved performance with power conversion efficiencies exceeding 9%. Moreover, good device performance was achievable with the PFEN-Hg over a wider range of film thickness, likely due to the Hg-Hg interactions and improved pi-pi stacking.
引用
收藏
页码:15326 / 15329
页数:4
相关论文
共 47 条
[1]   Molecular Design and Ordering Effects in π-Functional Materials for Transistor and Solar Cell Applications [J].
Beaujuge, Pierre M. ;
Frechet, Jean M. J. .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2011, 133 (50) :20009-20029
[2]   Electron energetics at surfaces and interfaces: Concepts and experiments [J].
Cahen, D ;
Kahn, A .
ADVANCED MATERIALS, 2003, 15 (04) :271-277
[3]   Morphology evolution via self-organization and lateral and vertical diffusion in polymer: fullerene solar cell blends [J].
Campoy-Quiles, Mariano ;
Ferenczi, Toby ;
Agostinelli, Tiziano ;
Etchegoin, Pablo G. ;
Kim, Youngkyoo ;
Anthopoulos, Thomas D. ;
Stavrinou, Paul N. ;
Bradley, Donal D. C. ;
Nelson, Jenny .
NATURE MATERIALS, 2008, 7 (02) :158-164
[4]   Interface investigation and engineering - achieving high performance polymer photovoltaic devices [J].
Chen, Li-Min ;
Xu, Zheng ;
Hong, Ziruo ;
Yang, Yang .
JOURNAL OF MATERIALS CHEMISTRY, 2010, 20 (13) :2575-2598
[5]   Recent Progress in Polymer Solar Cells: Manipulation of Polymer: Fullerene Morphology and the Formation of Efficient Inverted Polymer Solar Cells [J].
Chen, Li-Min ;
Hong, Ziruo ;
Li, Gang ;
Yang, Yang .
ADVANCED MATERIALS, 2009, 21 (14-15) :1434-1449
[6]   Synthesis of Conjugated Polymers for Organic Solar Cell Applications [J].
Cheng, Yen-Ju ;
Yang, Sheng-Hsiung ;
Hsu, Chain-Shu .
CHEMICAL REVIEWS, 2009, 109 (11) :5868-5923
[7]   Recent advances in water/alcohol-soluble π-conjugated materials: new materials and growing applications in solar cells [J].
Duan, Chunhui ;
Zhang, Kai ;
Zhong, Chengmei ;
Huang, Fei ;
Cao, Yong .
CHEMICAL SOCIETY REVIEWS, 2013, 42 (23) :9071-9104
[8]   Toward green solvent processable photovoltaic materials for polymer solar cells: the role of highly polar pendant groups in charge carrier transport and photovoltaic behavior [J].
Duan, Chunhui ;
Cai, Wanzhu ;
Hsu, Ben B. Y. ;
Zhong, Chengmei ;
Zhang, Kai ;
Liu, Chunchen ;
Hu, Zhicheng ;
Huang, Fei ;
Bazan, Guillermo C. ;
Heeger, Alan J. ;
Cao, Yong .
ENERGY & ENVIRONMENTAL SCIENCE, 2013, 6 (10) :3022-3034
[9]   Highly Efficient Inverted Polymer Solar Cells Based on an Alcohol Soluble Fullerene Derivative Interfacial Modification Material [J].
Duan, Chunhui ;
Zhong, Chengmei ;
Liu, Chunchen ;
Huang, Fei ;
Cao, Yong .
CHEMISTRY OF MATERIALS, 2012, 24 (09) :1682-1689
[10]   Toward high performance inverted polymer solar cells [J].
Gong, Xiong .
POLYMER, 2012, 53 (24) :5437-5448