Microporous crystal 12CaO•7Al2O3 encaging abundant O- radicals

被引：231

作者：

Hayashi, K ^{[1
]}

Hirano, M ^{[1
]}

Matsuishi, S ^{[1
]}

Hosono, H ^{[1
]}

机构：

[1] Japan Sci & Technol Corp, ERATO, Hosono Transparent Electroact Mat Project, Takatsu Ku, Kawasaki, Kanagawa 2130012, Japan

来源：

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY | 2002年 / 124卷 / 05期

关键词：

D O I：

10.1021/ja016112n

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Extremely high concentrations (>1020 cm-3) of active oxygenic radicals, O- and O2-, have been created in the zeolitic crystal, 12CaO·7Al2O3 (C12A7), which can accommodate anions in its cavities. An increase in oxygen pressure and a decrease in water vapor pressure at high temperature enhance the formation of the radicals. The oxidation of Pt is observed on the surface of the material as a result of reaction with the active oxygens. Copyright © 2002 American Chemical Society.

引用

页码：738 / 739

页数：2

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