SANS structural determination of a nonionic surfactant layer adsorbed on clay particles

被引:36
作者
Grillo, I
Levitz, P
Zemb, T
机构
[1] CEA Saclay, Serv Chim Mol, F-91191 Gif Sur Yvette, France
[2] CNRS, CRMD, F-45071 Orleans, France
关键词
D O I
10.1007/s100510050826
中图分类号
O469 [凝聚态物理学];
学科分类号
070205 ;
摘要
We study adsorption of two nonionic surfactants (C12E5 and C12E8) On a dispersed suspension of negatively charged laponite particles. First, we quantify adsorption, i.e. the amount of adsorbed molecules per gram of dried solid. Then, we show that contrast variation experiments under controlled conditions along the adsorption isotherm of the surfactant on dispersed laponite particles allow to determine the average thickness of a nonionic surfactant layer adsorbed on a solid anisotropic particle.
引用
收藏
页码:29 / 34
页数:6
相关论文
共 15 条
[1]   Dispersions of silica particles in surfactant phases [J].
Alexeev, VL ;
Ilekti, P ;
Persello, J ;
Lambard, J ;
Gulik, T ;
Cabane, B .
LANGMUIR, 1996, 12 (10) :2392-2401
[2]   STUDY OF THE ADSORPTION OF CATIONIC SURFACTANTS ON AQUEOUS LAPONITE CLAY SUSPENSIONS AND LAPONITE CLAY MODIFIED ELECTRODES [J].
BRAHIMI, B ;
LABBE, P ;
REVERDY, G .
LANGMUIR, 1992, 8 (08) :1908-1918
[3]  
CABANE B, 1985, NATURE, V314, P305
[4]  
DENOYEL R, 1987, THESIS U PROVENCE AI
[5]  
Guinier G Fournet A., 1955, SMALL ANGLE SCATTERI
[6]   Surfactant adsorption on a clay mineral: Application of radiation scattering [J].
Hanley, HJM ;
Muzny, CD ;
Butler, BD .
LANGMUIR, 1997, 13 (20) :5276-5282
[7]   DETERMINATION OF THE STRUCTURE OF A SURFACTANT LAYER ADSORBED AT THE SILICA WATER INTERFACE BY NEUTRON REFLECTION [J].
LEE, EM ;
THOMAS, RK ;
CUMMINS, PG ;
STAPLES, EJ ;
PENFOLD, J ;
RENNIE, AR .
CHEMICAL PHYSICS LETTERS, 1989, 162 (03) :196-202
[8]   AGGREGATIVE ADSORPTION OF NONIONIC SURFACTANTS ONTO HYDROPHILIC SOLID WATER INTERFACE - RELATION WITH BULK MICELLIZATION [J].
LEVITZ, P .
LANGMUIR, 1991, 7 (08) :1595-1608
[9]  
LINDNER P, 1991, N HOLLAND DELTA SERI
[10]   PHASE-BEHAVIOR OF POLYOXYETHYLENE SURFACTANTS WITH WATER - MESOPHASE STRUCTURES AND PARTIAL MISCIBILITY (CLOUD POINTS) [J].
MITCHELL, DJ ;
TIDDY, GJT ;
WARING, L ;
BOSTOCK, T ;
MCDONALD, MP .
JOURNAL OF THE CHEMICAL SOCIETY-FARADAY TRANSACTIONS I, 1983, 79 :975-1000