Preparation, XAFS characterization, and catalysis of platinum nanowires and nanoparticles in mesoporous silica FSM-16

被引:32
作者
Fukuoka, A [1 ]
Higashimoto, N
Sakamoto, Y
Inagaki, S
Fukushima, Y
Ichikawa, M
机构
[1] Hokkaido Univ, Catalysis Res Ctr, Sapporo, Hokkaido 0600811, Japan
[2] Toyota Cent Res & Dev Labs Inc, Aichi 4801192, Japan
关键词
nanowire; nanoparticle; FSM-16; mesopore; XAFS;
D O I
10.1023/A:1013886301858
中图分类号
O69 [应用化学];
学科分类号
081704 ;
摘要
Pt nanowires are prepared in mesoporous FSM-16 by photoreduction of H2PtCl6, while H-2-reduction of H2PtCl6/FSM-16 at 673 K gives Pt nanopatrticles in FSM-16. The Pt nanowires and nanoparticles are characterized by physicochemical methods such as XAFS, TEM, XRD, and XPS. The formation mechanism of the Pt nanowires and the catalytic performance in the water-gas-shift reaction are also investigated.
引用
收藏
页码:73 / 78
页数:6
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