Eastern Mediterranean sapropels: chemical structure, deposition and relation to oil-shales

被引：11

作者：

Dick, C

Ediger, V

Fabbri, D

Gaines, AF

Love, GD

McGinn, A

McRae, C

Murray, IP

Nicol, BJ

Snape, CE

机构：

[1] Univ Strathclyde, Dept Pure & Appl Chem, Glasgow G1 1XL, Lanark, Scotland

[2] Middle E Tech Univ, Inst Marine Sci, TR-33731 Icel, Turkey

[3] Univ Bologna, Dipartimento Chim G Ciamician, Lab Chim Ambientale, I-48100 Ravenna, Italy

[4] Newcastle Univ, Inst Fossil Fuels & Environm Geochem, Newcastle Upon Tyne NE1 7RU, Tyne & Wear, England

来源：

FUEL | 2002年 / 81卷 / 04期

基金：

英国自然环境研究理事会;

关键词：

sapropels; kerogen; pyrolysis-gas chromatography/mass spectrometry; CPMAS NMR; Hy-Py;

D O I：

10.1016/S0016-2361(01)00184-3

中图分类号：

TE [石油、天然气工业]; TK [能源与动力工程];

学科分类号：

0807 ; 0820 ;

摘要：

Ten sapropels, deposited in three different basins of the eastern Mediterranean since the Miocene and selected from cores of the Deep Sea Drilling Programme have been characterised by elemental analysis; fluorescence, infra-red and NMR spectrometry, by pyrolysis-gas chromatography/mass spectrometry and by catalytic hydrogenation at moderately high pressure. The sapropels are Types I-II kerogens, which have been oxidised, probably by a front experienced, since their deposition. Only one, from the Cretan basin, contained structures from lignin. The others, typical of a marine deposition, possessed aromaticities of about 0.2. Their detailed organic structures are described. (C) 2001 Elsevier Science Ltd. All rights reserved.

引用

页码：431 / 448

页数：18

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