Sintering and mechanical characteristics of lanthanum strontium manganite

被引:51
作者
Meixner, DL
Cutler, RA
机构
[1] Ceramatec Inc, Salt Lake City, UT 84119 USA
[2] Air Prod & Chem Inc, Salt Lake City, UT 84119 USA
关键词
lanthanum manganite; lanthanum strontium manganite; perovskite; oxygen nonstoichiometry; plastic deformation; creep; mechanical properties; SOFC;
D O I
10.1016/S0167-2738(01)01027-X
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
The sintering and mechanical characteristics of strontium-doped lanthanum manganites are increasingly important for both processing and device integration. A-site deficiency and reduced strontium fraction were shown to improve sinterability, High-strontium compositions displayed unusual mechanical properties, including unexpectedly low Young's modulus and fracture strength. In addition, plastic deformation of a fully dense LSM plate under modest loading was observed. This surprising and novel result may result from oxygen exchange with the LSM surface at elevated temperatures. (C) 2002 Elsevier Science B.V. All rights reserved.
引用
收藏
页码:273 / 284
页数:12
相关论文
共 33 条
[1]   Kinetics of oxidation of fuel cell cathode materials lanthanum strontium Manganates(III)(IV) at actual working conditions:: In situ powder diffraction studies [J].
Andersen, EK ;
Andersen, IGK ;
Norby, P ;
Hanson, JC .
JOURNAL OF SOLID STATE CHEMISTRY, 1998, 141 (01) :235-240
[2]  
[Anonymous], ANN BOOK ASTM STAND
[3]   Mechanical behaviour of ceramic oxygen ion-conducting membranes [J].
Atkinson, A ;
Selçuk, A .
SOLID STATE IONICS, 2000, 134 (1-2) :59-66
[4]   Surprising results of a study on the plasticity in strontium titanate [J].
Brunner, D ;
Taeri-Baghbadrani, S ;
Sigle, W ;
Rühle, M .
JOURNAL OF THE AMERICAN CERAMIC SOCIETY, 2001, 84 (05) :1161-1163
[5]   Grain growth in CeO2: Dopant effects, defect mechanism, and solute drag [J].
Chen, PL ;
Chen, IW .
JOURNAL OF THE AMERICAN CERAMIC SOCIETY, 1996, 79 (07) :1793-1800
[6]   Phase equilibria in the La-Sr-Mn-O system [J].
Cherepanov, VA ;
Barkhatova, LY ;
Voronin, VI .
JOURNAL OF SOLID STATE CHEMISTRY, 1997, 134 (01) :38-44
[7]   Mechanical properties of La1-xSrxCo0.2Fe0.8O3 mixed-conducting perovskites made by the combustion synthesis technique [J].
Chou, YS ;
Stevenson, JW ;
Armstrong, TR ;
Pederson, LR .
JOURNAL OF THE AMERICAN CERAMIC SOCIETY, 2000, 83 (06) :1457-1464
[8]   Mechanical properties of strontium-doped lanthanum manganite [J].
D'Souza, CM ;
Sammes, NM .
JOURNAL OF THE AMERICAN CERAMIC SOCIETY, 2000, 83 (01) :47-52
[9]   Formation add migration of cation defects in the perovskite oxide LaMnO3 [J].
De Souza, RA ;
Islam, MS ;
Ivers-Tiffée, E .
JOURNAL OF MATERIALS CHEMISTRY, 1999, 9 (07) :1621-1627
[10]   CRYSTALLOGRAPHIC, THERMAL AND ELECTROCHEMICAL PROPERTIES OF THE SYSTEM LA1-XSRXMNO3 FOR HIGH-TEMPERATURE SOLID ELECTROLYTE FUEL-CELLS [J].
HAMMOUCHE, A ;
SIEBERT, E ;
HAMMOU, A .
MATERIALS RESEARCH BULLETIN, 1989, 24 (03) :367-380