Exploring the re-evaluated interpretation of hydrophobicity to explain rates of Diels-Alder reactions in aqueous salt solutions

被引：9

作者：

Kumar, A ^{[1
]}

Deshpande, SS ^{[1
]}

机构：

[1] Natl Chem Lab, Div Phys Chem, Pune 411008, Maharashtra, India

来源：

JOURNAL OF PHYSICAL ORGANIC CHEMISTRY | 2002年 / 15卷 / 04期

关键词：

Diels-Alder reaction; salt effect; reaction rates; hydrophobicity; internal pressure; endo/exo ratios;

D O I：

10.1002/poc.473

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

The recently proposed correlation between hydrophobicity and internal pressure offers quantitative support to our understanding on the rate enhancement of Diels-Alder reactions in water and its salt solutions. Copyright (C) 2002-John Wiley Sons, Ltd.

引用

页码：242 / 245

页数：4

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