Exploring the Reactivity of C(sp3)-Cyclometalated IrIII Compounds in Hydrogen Transfer Reactions

被引：58

作者：

Azerraf, Clarite ^{[1
]}

Gelman, Dmitri ^{[1
]}

机构：

[1] Hebrew Univ Jerusalem, Inst Chem, IL-91904 Jerusalem, Israel

来源：

CHEMISTRY-A EUROPEAN JOURNAL | 2008年 / 14卷 / 33期

基金：

以色列科学基金会;

关键词：

cyclometalation; hydrogenation; iridium; P ligands; pincer complexes;

D O I：

10.1002/chem.200801728

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The manuscript describes the synthesis and full characterization of a new PC(sp(3))P-based cyclometalated Ir-III complex that manifests all exceptional thermal stability, as well as outstanding reactivity in hydrogen transfer reactions. The described compound represents the first example of a new family of stable C-(sp(3))-metalated compounds.

引用

页码：10364 / 10368

页数：5

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