Synthesis of enantiopure cis-decalins from microbially-derived cis-1,2-dihydrocatechols

被引：25

作者：

Banwell, MG ^{[1
]}

Dupuche, JR ^{[1
]}

机构：

[1] UNIV MELBOURNE,SCH CHEM,PARKVILLE,VIC 3052,AUSTRALIA

来源：

CHEMICAL COMMUNICATIONS | 1996年 / 07期

关键词：

D O I：

10.1039/cc9960000869

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The microbially-derived cis-1,2-dihydrocatechol 3 is converted, via reaction sequences involving Diels-Alder cycloaddition and anionic oxy-Cope rearrangement steps, into the enantiopure cis-decalins 15 and 26; using simple modifications of this chemistry the pseudo-enantiomer 22 of decalin 15 is also prepared from diol 3.

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收藏

页码：869 / 870

页数：2

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