Ultra-thin high efficiency semitransparent perovskite solar cells

被引:314
作者
Della Gaspera, Enrico [1 ]
Peng, Yong [2 ]
Hou, Qicheng [2 ]
Spiccia, Leone [3 ]
Bach, Udo [1 ,2 ,4 ]
Jasieniak, Jacek J. [1 ]
Cheng, Yi-Bing [2 ]
机构
[1] CSIRO Mfg Flagship, Clayton, Vic 3168, Australia
[2] Monash Univ, Dept Mat Sci & Engn, Clayton, Vic 3800, Australia
[3] Monash Univ, Sch Chem, Clayton, Vic 3800, Australia
[4] Melbourne Ctr Nanofabricat, Clayton, Vic 3168, Australia
基金
澳大利亚研究理事会;
关键词
Transparent electrode; Molybdenum oxide; Photovoitaics; Methylammonium lead iodide; Thin film; LOW-COST; HYSTERESIS; ELECTRODES; DEPOSITION; SIZE;
D O I
10.1016/j.nanoen.2015.02.028
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
Solar cells based on organometal trihalide perovskite light absorbers have recently emerged as one of the most promising class of photovoltaic devices. Given their high performances, along with their low fabrication costs, such devices are appealing for building integrated photovoltaics, especially if made semitransparent and used as solar windows. In this study, efficient perovskite solar cells with high transparency in the visible spectrum have been developed. These devices comprise a dielectric-metal-dielectric multilayered top electrode with high transparency and conductivity, and an optimized solution-based thin and continuous methylammonium lead iodide film. Through this combination of processing and device architecture developments, semitransparent solar cells with high visible transmittance and record power conversion efficiency have been prepared, including devices with a perovskite thickness as low as 55 nm. (C) 2015 Elsevier Ltd. All rights reserved.
引用
收藏
页码:249 / 257
页数:9
相关论文
共 41 条
[1]   Efficient planar heterojunction mixed-halide perovskite solar cells deposited via spray-deposition [J].
Barrows, Alexander T. ;
Pearson, Andrew J. ;
Kwak, Chan Kyu ;
Dunbar, Alan D. F. ;
Buckley, Alastair R. ;
Lidzey, David G. .
ENERGY & ENVIRONMENTAL SCIENCE, 2014, 7 (09) :2944-2950
[2]   Sequential deposition as a route to high-performance perovskite-sensitized solar cells [J].
Burschka, Julian ;
Pellet, Norman ;
Moon, Soo-Jin ;
Humphry-Baker, Robin ;
Gao, Peng ;
Nazeeruddin, Mohammad K. ;
Graetzel, Michael .
NATURE, 2013, 499 (7458) :316-+
[3]   Flexible organic solar cells using an oxide/metal/oxide trilayer as transparent electrode [J].
Cao, Weiran ;
Zheng, Ying ;
Li, Zhifeng ;
Wrzesniewski, Edward ;
Hammond, William T. ;
Xue, Jiangeng .
ORGANIC ELECTRONICS, 2012, 13 (11) :2221-2228
[4]   Toward indium-free optoelectronic devices: Dielectric/metal/dielectric alternative transparent conductive electrode in organic photovoltaic cells [J].
Cattin, L. ;
Bernede, J. C. ;
Morsli, M. .
PHYSICA STATUS SOLIDI A-APPLICATIONS AND MATERIALS SCIENCE, 2013, 210 (06) :1047-1061
[5]   Silver Nanowire Composite Window Layers for Fully Solution-Deposited Thin-Film Photovoltaic Devices [J].
Chung, Choong-Heui ;
Song, Tze-Bin ;
Bob, Brion ;
Zhu, Rui ;
Duan, Hsin-Sheng ;
Yang, Yang .
ADVANCED MATERIALS, 2012, 24 (40) :5499-5504
[6]   Efficient, Semitransparent Neutral-Colored Solar Cells Based on Microstructured Formamidinium Lead Trihalide Perovskite [J].
Eperon, Giles E. ;
Bryant, Daniel ;
Troughton, Joel ;
Stranks, Samuel D. ;
Johnston, Michael B. ;
Watson, Trystan ;
Worsley, David A. ;
Snaith, Henry J. .
JOURNAL OF PHYSICAL CHEMISTRY LETTERS, 2015, 6 (01) :129-138
[7]   Neutral Color Semitransparent Microstructured Perovskite Solar Cells [J].
Eperon, Giles E. ;
Burlakov, Victor M. ;
Goriely, Alain ;
Snaith, Henry J. .
ACS NANO, 2014, 8 (01) :591-598
[8]   Transparent conducting oxides for photovoltaics [J].
Fortunato, Elvira ;
Ginley, David ;
Hosono, Hideo ;
Paine, David C. .
MRS BULLETIN, 2007, 32 (03) :242-247
[9]   Fully Solution-Processed Inverted Polymer Solar Cells with Laminated Nanowire Electrodes [J].
Gaynor, Whitney ;
Lee, Jung-Yong ;
Peumans, Peter .
ACS NANO, 2010, 4 (01) :30-34
[10]   RADIATIVE HEATING AND COOLING WITH SPECTRALLY SELECTIVE SURFACES [J].
GRANQVIST, CG .
APPLIED OPTICS, 1981, 20 (15) :2606-2615