Superhydrophobicity from composite nano/microstructures: Carbon fabrics coated with silica nanoparticles

被引:99
作者
Hsieh, Chien-Te [1 ]
Wu, Fang-Lin [1 ]
Yang, Shu-Ying [1 ]
机构
[1] Yuan Ze Univ, Yuan Ze Fuel Cell Ctr, Dept Chem Engn & Mat Sci, Tao Yuan 320, Taiwan
关键词
Two-tier nano/microstructure; Superhydrophobicity; Carbon fabric; Silica nanoparticle; Contact angle hysteresis;
D O I
10.1016/j.surfcoat.2008.07.006
中图分类号
TB3 [工程材料学];
学科分类号
0805 ; 080502 ;
摘要
This study demonstrates the hydrophobic coating of silica nanoparticles onto microscaled carbon fabrics (CFs) and investigates the superhydrophobic behavior of composite nano/microstructures. The two-tier composite surfaces are based on regularly ordered carbon fibers (8-10 mu m in diameter) that are coated with SiO2 nanoparticles with an average size of 300-500 nm. The microscale fiber is used here as the primary Surface roughness, while the silica nanoparticles serve as the secondary roughness, mimicking the lotus leaf in nature. Increasing the density of silica on Us showed significant effects on the enhancement of static contact angle, decrease of contact angle hysteresis, and superhydrophobic stability. The results can be attributed to the fact that the higher density of silica coating results in more tortuous three-phase contact line, thus facilitating the self-cleaning effect. (c) 2008 Elsevier B.V. All rights reserved.
引用
收藏
页码:6103 / 6108
页数:6
相关论文
共 28 条
[1]   Silicone nanofilaments and their application as superhydrophobic coating [J].
Artus, Georg R. J. ;
Jung, Stefan ;
Zimmermann, Jan ;
Gautschi, Hans-Peter ;
Marquardt, Klaus ;
Seeger, Stefan .
ADVANCED MATERIALS, 2006, 18 (20) :2758-+
[2]   Self-cleaning surfaces - virtual realities [J].
Blossey, R .
NATURE MATERIALS, 2003, 2 (05) :301-306
[3]   Dropwise condensation on superhydrophobic surfaces with two-tier roughness [J].
Chen, Chuan-Hua ;
Cai, Qingjun ;
Tsai, Chialun ;
Chen, Chung-Lung ;
Xiong, Guangyong ;
Yu, Ying ;
Ren, Zhifeng .
APPLIED PHYSICS LETTERS, 2007, 90 (17)
[4]   Ultrahydrophobic and ultralyophobic surfaces:: Some comments and examples [J].
Chen, W ;
Fadeev, AY ;
Hsieh, MC ;
Öner, D ;
Youngblood, J ;
McCarthy, TJ .
LANGMUIR, 1999, 15 (10) :3395-3399
[5]   Silica xerogels of tailored porosity as support matrix for optical chemical sensors.: Simultaneous effect of pH, ethanol:TEOS and water:TEOS molar ratios, and synthesis temperature on gelation time, and textural and structural properties [J].
Estella, Juncal ;
Echeverria, Jesus C. ;
Laguna, Mariano ;
Garrido, Julian J. .
JOURNAL OF NON-CRYSTALLINE SOLIDS, 2007, 353 (03) :286-294
[6]   The defect structure of sol-gel-derived silica/polytetrahydrofuran hybrid films by FTIR [J].
Fidalgo, A ;
Ilharco, LM .
JOURNAL OF NON-CRYSTALLINE SOLIDS, 2001, 283 (1-3) :144-154
[7]   A modified Wenzel model for hydrophobic behavior of nanostructured surfaces [J].
Han, Tao-Yun ;
Shr, Jin-Fang ;
Wu, Chu-Fu ;
Hsieh, Chien-Te .
THIN SOLID FILMS, 2007, 515 (11) :4666-4669
[8]   Superhydrophobicity of a material made from multiwalled carbon nanotubes [J].
Hong, Yong Cheol ;
Uhm, Han Sup .
APPLIED PHYSICS LETTERS, 2006, 88 (24)
[9]   Superhydrophobic behavior of fluorinated carbon nanofiber arrays [J].
Hsieh, CT ;
Fan, WS .
APPLIED PHYSICS LETTERS, 2006, 88 (24)
[10]   Influence of fluorine/carbon atomic ratio on superhydrophobic behavior of carbon nanofiber arrays [J].
Hsieh, CT ;
Chen, JM ;
Huang, YH ;
Kuo, RR ;
Li, CT ;
Shih, HC ;
Lin, TS ;
Wu, CF .
JOURNAL OF VACUUM SCIENCE & TECHNOLOGY B, 2006, 24 (01) :113-117