Methods for fabricating and characterizing a new generation of biomimetic materials

被引:90
作者
Almqvist, N [1 ]
Thomson, NH
Smith, BL
Stucky, GD
Morse, DE
Hansma, PK
机构
[1] Univ Calif Santa Barbara, Dept Phys, Santa Barbara, CA 93106 USA
[2] Univ Calif Santa Barbara, Dept Chem, Santa Barbara, CA 93106 USA
[3] Univ Calif Santa Barbara, Dept Mol Cellar & Dev Biol, Santa Barbara, CA 93106 USA
[4] Univ Lulea, Dept Phys, S-97187 Lulea, Sweden
来源
MATERIALS SCIENCE & ENGINEERING C-BIOMIMETIC AND SUPRAMOLECULAR SYSTEMS | 1999年 / 7卷 / 01期
基金
美国国家科学基金会; 英国工程与自然科学研究理事会;
关键词
biomineralization; talc; polyvinylacetate; orienting; x-ray; SEM; biomimetics;
D O I
10.1016/S0928-4931(98)00072-1
中图分类号
T [工业技术];
学科分类号
08 [工学];
摘要
Bringing together current ideas in the fields of biomineralization and composite laminate materials, we have attempted to fabricate model materials that mimic abalone nacre through the rapid assembly of inorganic tablets, such as talc. Several physical methods were tested to aid the orientation of the talc tablets in fluid suspensions with a low percentage, 10% by dry weight, of organic binding material. The orientation of talc tablets in the synthesized composites was characterized by X-ray diffraction and scanning electron microscopy. The modulus of rupture of the materials was measured in a three-point bending test. We demonstrate that the alignment of tablets increases by the use of physical methods and from chemical surface treatment. Important factors to consider in making materials that mimic abalone nacre are discussed. Important factors to consider in making materials that mimic abalone nacre are discussed. (C) 1999 Elsevier Science S.A. All rights reserved.
引用
收藏
页码:37 / 43
页数:7
相关论文
共 31 条
[1]
Control of crystal phase switching and orientation by soluble mollusc-shell proteins [J].
Belcher, AM ;
Wu, XH ;
Christensen, RJ ;
Hansma, PK ;
Stucky, GD ;
Morse, DE .
NATURE, 1996, 381 (6577) :56-58
[2]
CURREY JD, 1977, PROC R SOC SER B-BIO, V196, P443, DOI 10.1098/rspb.1977.0050
[3]
Control of aragonite or calcite polymorphism by mollusk shell macromolecules [J].
Falini, G ;
Albeck, S ;
Weiner, S ;
Addadi, L .
SCIENCE, 1996, 271 (5245) :67-69
[4]
Polymer layered silicate nanocomposites [J].
Giannelis, EP .
ADVANCED MATERIALS, 1996, 8 (01) :29-&
[5]
INORGANIC OVERGROWTH OF ARAGONITE ON MOLLUSCAN NACRE EXAMINED BY ATOMIC-FORCE MICROSCOPY [J].
GILES, R ;
MANNE, S ;
MANN, S ;
MORSE, DE ;
STUCKY, GD ;
HANSMA, PK .
BIOLOGICAL BULLETIN, 1995, 188 (01) :8-15
[6]
HURLBUT CS, 1985, MANUAL MIENRALOGY, P418
[7]
THE MECHANICAL DESIGN OF NACRE [J].
JACKSON, AP ;
VINCENT, JFV ;
TURNER, RM .
PROCEEDINGS OF THE ROYAL SOCIETY SERIES B-BIOLOGICAL SCIENCES, 1988, 234 (1277) :415-+
[8]
COMPARISON OF NACRE WITH OTHER CERAMIC COMPOSITES [J].
JACKSON, AP ;
VINCENT, JFV ;
TURNER, RM .
JOURNAL OF MATERIALS SCIENCE, 1990, 25 (07) :3173-3178
[9]
Rheology of dense suspensions of platelike particles [J].
Jogun, S ;
Zukoski, CF .
JOURNAL OF RHEOLOGY, 1996, 40 (06) :1211-1232
[10]
CRYSTALLIZATION AT INORGANIC-ORGANIC INTERFACES - BIOMINERALS AND BIOMIMETIC SYNTHESIS [J].
MANN, S ;
ARCHIBALD, DD ;
DIDYMUS, JM ;
DOUGLAS, T ;
HEYWOOD, BR ;
MELDRUM, FC ;
REEVES, NJ .
SCIENCE, 1993, 261 (5126) :1286-1292