Synthesis of CuO nanostructures from Cu-based metal organic framework (MOE-199) for application as anode for Li-ion batteries

被引：244

作者：

Banerjee, Abhik ^{[1
,2
]}

Singh, Upendra ^{[1
,2
]}

Aravindan, Vanchiappan ^{[3
]}

Srinivasan, Madhavi ^{[3
,4
]}

Ogale, Satishchandra ^{[1
,2
]}

机构：

[1] Natl Chem Lab CSIR NCL, Ctr Excellence Solar Energy, Pune, Maharashtra, India

[2] Network Inst Solar Energy CSIR NISE, New Delhi, India

[3] Nanyang Technol Univ, Energy Res Inst NTU ERI N, Singapore 637553, Singapore

[4] Nanyang Technol Univ, Sch Mat Sci & Engn, Singapore 639798, Singapore

来源：

NANO ENERGY | 2013年 / 2卷 / 06期

基金：

新加坡国家研究基金会;

关键词：

Li ion battery; CuO; Metal organic framework; Anode; ELECTRODE MATERIALS; LITHIUM; PERFORMANCE; NANOCOMPOSITE; MICROSPHERES; FABRICATION; CATALYSTS; TEMPLATE; STORAGE; MOF;

D O I：

10.1016/j.nanoen.2013.04.008

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

We report the synthesis of CuO nanostructures by metal organic framework (MOF) based approach. Spherical shaped, phase pure CuO nanoparticles are obtained by controlled pyrolysis of Cu-based MOF. Electrochemical properties are evaluated in half-cell assembly and it is found that similar to 1.6 mol of Li (similar to 538 mAh g(-1)) is cycleable via conversion reaction. Further, MOF derived CuO retained 90% of initial reversible capacity after 40 cycles. Rate performance studies showed the deliverable reversible capacity of similar to 210 mAh g(-1) at high current rate of 2 A g(-1). (C) 2013 Elsevier Ltd. All rights reserved.

引用

页码：1158 / 1163

页数：6

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