Oxidation Catalysts for Elemental Mercury in Flue Gases-A Review

被引：92

作者：

Dranga, Beatrice-Andreea ^{[1
,2
]}

Lazar, Liliana ^{[1
]}

Koeser, Heinz ^{[2
]}

机构：

[1] Gheorghe Asachi Tech Univ Iasi, Fac Chem Engn & Environm Protect, Dept Chem Engn, Iasi 700050, Romania

[2] Univ Halle Wittenberg, Engn Sci Ctr, Univ Magdeburg, D-06099 Halle, Saale, Germany

来源：

CATALYSTS | 2012年 / 2卷 / 01期

关键词：

mercury oxidation; catalysts; Hgel oxidation mechanisms; SCR; noble metal; transition metal oxide; REDUCTION SCR; REMOVAL; MECHANISM; ADSORPTION; SPECIATION; EMISSIONS; CAPTURE; GOLD; CONVERSION; PALLADIUM;

D O I：

10.3390/catal2010139

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070305 [高分子化学与物理];

摘要：

The removal of mercury from flue gases in scrubbers is greatly facilitated if the mercury is present as water-soluble oxidized species. Therefore, increased mercury oxidation upstream of scrubber devices will improve overall mercury removal. For this purpose heterogeneous catalysts have recently attracted a great deal of interest. Selective catalytic reduction (SCR), noble metal and transition metal oxide based catalysts have been investigated at both the laboratory and plant scale with this objective. A review article published in 2006 covers the progress in the elemental mercury (Hg-el) catalytic oxidation area. This paper brings the review in this area up to date. To this end, 110 papers including several reports and patents are reviewed. For each type of catalyst the possible mechanisms as well as the effect of flue gas components on activity and stability are examined. Advantages and main problems are analyzed. The possible future directions of catalyst development in this environmental research area are outlined.

引用

页码：139 / 170

页数：32

共 113 条

[1]

[Anonymous], 2010, OJ

[2]

Bierogel S., 2003, CHEM-ING-TECH, V75, P1066

[3]

Blythe G., 2006, Pilot testing of mercury oxidation catalysts for upstream of Wet FGD systems

[4]

Blythe G., 2008, P POW PLANT AIR POLL

[5]

Blythe M.G., 2010, FULL SCALE TESTING M

[6]

Blythe M.G., 2010, PILOT TESTING MERCUR

[7]

Bond G.C., 2006, CATALYSIS GOLD, DOI 10.1007/bf03215560

[8]

BORESKOV GK, 1953, DOKL AKAD NAUK SSSR+, V92, P109

[9]

Impacts of halogen additions on mercury oxidation, in a slipstream selective catalyst reduction (SCR), reactor when burning sub-bituminous coal [J].

Cao, Yan ;

Gao, Zhengyang ;

Zhu, Jiashun ;

Wang, Quanhai ;

Huang, Yaji ;

Chiu, Chengchung ;

Parker, Bruce ;

Chu, Paul ;

Pan, Wei-Ping .

ENVIRONMENTAL SCIENCE & TECHNOLOGY, 2008, 42 (01) :256-261

[10]

Study of mercury oxidation by a selective catalytic reduction catalyst in a pilot-scale slipstream reactor at a utility boiler burning bituminous coal [J].

Cao, Yan ;

Chen, Bobby ;

Wu, Jiang ;

Cui, Hong ;

Smith, John ;

Chen, Chi-Kuan ;

Chu, Paul ;

Pan, Wei-Ping .

ENERGY & FUELS, 2007, 21 (01) :145-156

← 1 2 3 4 5 6 7 8 9 10 →