Regularly interstratified layered silicate heterostructures: Precursors to pillared rectorite-like intercalates

被引:41
作者
IJdo, WL
Lee, T
Pinnavaia, TJ
机构
[1] MICHIGAN STATE UNIV,DEPT CHEM,E LANSING,MI 48824
[2] MICHIGAN STATE UNIV,CTR FUNDAMENTAL MAT RES,E LANSING,MI 48824
关键词
D O I
10.1002/adma.19960080117
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
A fundamental advance in the intercalation chemistry of clays is the formation for the first time of smectite clay heterostructures with regularly stratified organic and inorganic exchange cations, e.g. the fluorohectorite heterostructure with gallery cations Na+ and C16H33PBU3+ shown in the figure. Their transformation into rectorite-like alumina pillared analogues is also demonstrated.
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页码:79 / &
页数:6
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