Reactions over catalysts confined in carbon nanotubes

被引:241
作者
Pan, Xiulian [1 ]
Bao, Xinhe [1 ]
机构
[1] Dalian Inst Chem Phys, State Key Lab Catalysis, Dalian 116023, Peoples R China
关键词
D O I
10.1039/b810994j
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
We review a new concept for modifying the redox properties of transition metals via confinement within the channels of carbon nanotubes (CNTs), and thus tuning their catalytic performance. Attention is also devoted to novel techniques for homogeneous dispersion of metal nanoparticles inside CNTs since these are essential for optimization of the catalytic activity.
引用
收藏
页码:6271 / 6281
页数:11
相关论文
共 70 条
[1]   OPENING CARBON NANOTUBES WITH OXYGEN AND IMPLICATIONS FOR FILLING [J].
AJAYAN, PM ;
EBBESEN, TW ;
ICHIHASHI, T ;
IIJIMA, S ;
TANIGAKI, K ;
HIURA, H .
NATURE, 1993, 362 (6420) :522-525
[2]   Carbons as supports for industrial precious metal catalysts [J].
Auer, E ;
Freund, A ;
Pietsch, J ;
Tacke, T .
APPLIED CATALYSIS A-GENERAL, 1998, 173 (02) :259-271
[3]   Cutting single-walled carbon nanotubes with an electron beam: Evidence for atom migration inside nanotubes [J].
Banhart, F ;
Li, JX ;
Terrones, M .
SMALL, 2005, 1 (10) :953-956
[4]   Cobalt on carbon nanofiber catalysts: auspicious system for study of manganese promotion in Fischer-Tropsch catalysis [J].
Bezemer, GL ;
Falke, U ;
van Dillen, AJ ;
de Jong, KP .
CHEMICAL COMMUNICATIONS, 2005, (06) :731-733
[5]   HYBRIDIZATION EFFECTS AND METALLICITY IN SMALL RADIUS CARBON NANOTUBES [J].
BLASE, X ;
BENEDICT, LX ;
SHIRLEY, EL ;
LOUIE, SG .
PHYSICAL REVIEW LETTERS, 1994, 72 (12) :1878-1881
[6]   Reducing reaction of Fe3O4 in nanoscopic reactors of a-CNTs [J].
Cao, Fangyu ;
Zhong, Kaifu ;
Gao, Aimei ;
Chen, Changle ;
Li, Quanxin ;
Chen, Qianwang .
JOURNAL OF PHYSICAL CHEMISTRY B, 2007, 111 (07) :1724-1728
[7]   Filling double-walled carbon nanotubes with AgCl nanowires [J].
Chen, Gang ;
Qiu, Jieshan ;
Qiu, Hanxun .
SCRIPTA MATERIALIA, 2008, 58 (06) :457-460
[8]   Facile autoreduction of iron oxide/carbon nanotube encapsulates [J].
Chen, W ;
Pan, XL ;
Willinger, MG ;
Su, DS ;
Bao, XH .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2006, 128 (10) :3136-3137
[9]   Effect of confinement in carbon nanotubes on the activity of Fischer-Tropsch iron catalyst [J].
Chen, Wei ;
Fan, Zhongli ;
Pan, Xiulian ;
Bao, Xinhe .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2008, 130 (29) :9414-9419
[10]   Tuning of redox properties of iron and iron oxides via encapsulation within carbon nanotubes [J].
Chen, Wei ;
Pan, Xiulian ;
Bao, Xinhe .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2007, 129 (23) :7421-7426