Synthesis and Properties of New Phosphorescent Red Light-Excitable Platinum(II) and Palladium(II) Complexes with Schiff Bases for Oxygen Sensing and Triplet-Triplet Annihilation-Based Upconversion

被引：95

作者：

Borisov, Sergey M. ^{[1
]}

Saf, Robert ^{[2
]}

Fischer, Roland ^{[3
]}

Klimant, Ingo ^{[1
]}

机构：

[1] Graz Univ Technol, Inst Analyt Chem & Food Chem, A-8010 Graz, Austria

[2] Graz Univ Technol, Inst Chem & Technol Mat, A-8010 Graz, Austria

[3] Graz Univ Technol, Inst Inorgan Chem, A-8010 Graz, Austria

来源：

INORGANIC CHEMISTRY | 2013年 / 52卷 / 03期

基金：

欧洲研究理事会;

关键词：

NEAR-IR PHOSPHORESCENCE; LOW-POWER; EXCITED-STATES; VISIBLE-LIGHT; EMITTING-DIODES; HIGH-EFFICIENCY; QUANTUM YIELDS; TEMPERATURE; POLYMER; SENSITIZERS;

D O I：

10.1021/ic301440k

中图分类号：

O61 [无机化学];

学科分类号：

070301 [无机化学];

摘要：

New Pt(II) and Pd(II) complexes with donor-acceptor Schiff bases are conveniently prepared in only two steps. The complexes efficiently absorb in the red part of the spectrum (epsilon > 10(5) M-1 cm(-1)) and show moderate to strong room-temperature phosphorescence in the near-infrared (NIR) region. Particularly, Pt(H) complexes possess phosphorescence quantum yields (Phi) of similar to 10%, but the emission of the respective Pd(II) complexes is less efficient (Phi approximate to 1%-2%). The complexes exhibit solvatochromic behavior, in which the absorption and emission spectra shift bathochromically in polar solvents. The Pt(II) complexes are embedded in polystyrene to produce oxygen-sensing materials. The Pd(II) and Pt(II) complexes are demonstrated to be efficient sensitizers in triplet-triplet annihilation-based upconversion systems.

引用

页码：1206 / 1216

页数：11

共 71 条

[1]

Optical oxygen sensor devices using metalloporphyrins [J].

Amao, Yutaka ;

Okura, Ichiro .

JOURNAL OF PORPHYRINS AND PHTHALOCYANINES, 2009, 13 (11) :1111-1122

[2]

[Anonymous], 1994, SHELX SHELXL PC VERS

[3]

[Anonymous], 1995, SADABS AR DET ADS CO

[4]

Lighting the way to see inside the live cell with luminescent transition metal complexes [J].

Baggaley, Elizabeth ;

Weinstein, Julia A. ;

Williams, J. A. Gareth .

COORDINATION CHEMISTRY REVIEWS, 2012, 256 (15-16) :1762-1785

[5]

Upconversion with ultrabroad excitation band: Simultaneous use of two sensitizers [J].

Baluschev, S. ;

Yakutkin, V. ;

Wegner, G. ;

Miteva, T. ;

Nelles, G. ;

Yasuda, A. ;

Chernov, S. ;

Aleshchenkov, S. ;

Cheprakov, A. .

APPLIED PHYSICS LETTERS, 2007, 90 (18)

[6]

Highly efficient, near-infrared electrophosphorescence from a Pt-metalloporphyrin complex [J].

Borek, Carsten ;

Hanson, Kenneth ;

Djurovich, Peter I. ;

Thompson, Mark E. ;

Aznavour, Kristen ;

Bau, Robert ;

Sun, Yiru ;

Forrest, Stephen R. ;

Brooks, Jason ;

Michalski, Lech ;

Brown, Julie .

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2007, 46 (07) :1109-1112

[7]

Red Light-Excitable Oxygen Sensing Materials Based on Platinum(II) and Palladium(II) Benzoporphyrins [J].

Borisov, S. M. ;

Nuss, G. ;

Klimant, I. .

ANALYTICAL CHEMISTRY, 2008, 80 (24) :9435-9442

[8]

Photophysical properties of the new phosphorescent platinum(II) and palladium(II) complexes of benzoporphyrins and chlorins [J].

Borisov, S. M. ;

Papkovsky, D. B. ;

Ponomarev, G. V. ;

DeToma, A. S. ;

Saf, R. ;

Klimant, I. .

JOURNAL OF PHOTOCHEMISTRY AND PHOTOBIOLOGY A-CHEMISTRY, 2009, 206 (01) :87-92

[9]

New NIR-emitting complexes of platinum(II) and palladium(II) with fluorinated benzoporphyrins [J].

Borisov, S. M. ;

Nuss, G. ;

Haas, W. ;

Saf, R. ;

Schmuck, M. ;

Klimant, I. .

JOURNAL OF PHOTOCHEMISTRY AND PHOTOBIOLOGY A-CHEMISTRY, 2009, 201 (2-3) :128-135

[10]

Triplet-Triplet Annihilation-Based Anti-Stokes Oxygen Sensing Materials with a Very Broad Dynamic Range [J].

Borisov, Sergey M. ;

Larndorfer, Christoph ;

Klimant, Ingo .

ADVANCED FUNCTIONAL MATERIALS, 2012, 22 (20) :4360-4368

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