Is [Co4(H2O)2(α-PW9O34)2]10- a genuine molecular catalyst in photochemical water oxidation? Answers from time-resolved hole scavenging experiments

被引：85

作者：

Natali, Mirco ^{[3
,4
]}

Berardi, Serena ^{[1
,2
]}

Sartorel, Andrea ^{[1
,2
]}

Bonchio, Marcella ^{[1
,2
]}

Campagna, Sebastiano ^{[5
,6
]}

Scandola, Franco ^{[3
,4
]}

机构：

[1] Univ Padua, ITM CNR, I-35131 Padua, Italy

[2] Univ Padua, Dipartimento Sci Chim, I-35131 Padua, Italy

[3] Univ Ferrara, Dipartimento Chim, I-44121 Ferrara, Italy

[4] Ctr Interuniv Convers Chim Energia Solare, Sez Ferrara, I-44121 Ferrara, Italy

[5] Ctr Interuniv Convers Chim Energia Solare, Sez Messina, I-98166 Messina, Italy

[6] Univ Messina, Dipartimento Chim Inorgan Chim Analit & Chim Fis, I-98166 Messina, Italy

来源：

CHEMICAL COMMUNICATIONS | 2012年 / 48卷 / 70期

关键词：

OXYGEN-EVOLVING CATALYST; ELECTRON-TRANSFER; PHOTOSYSTEM-II; POLYOXOMETALATE; COBALT; MANGANESE; COMPLEX;

D O I：

10.1039/c2cc34804g

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Water oxidation catalysts: evolution of [Co-4(H2O)(2)(alpha-PW9O34)(2)](10-) to catalytically active species is assessed by laser flash photolysis in sacrificial photocatalytic cycles with Ru(bpy)(3)(2+) as a photosensitizer.

引用

页码：8808 / 8810

页数：3

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