Diffusion from a three-phase junction into a hemispherical droplet

被引:13
作者
Lovric, M [1 ]
机构
[1] Rudjer Boskovic Inst, Ctr Marine Res Zagreb, HR-10001 Zagreb, Croatia
关键词
hemispherical diffusion; ionic liquids; cyclic voltammetry; three-phase junction;
D O I
10.1016/S1388-2481(99)00040-5
中图分类号
O646 [电化学、电解、磁化学];
学科分类号
081704 ;
摘要
A diffusion of ions from the three-phase boundary into a hemispherical oily microdroplet deposited on an inert solid electrode and immersed in aqueous electrolyte is calculated by the finite difference method. The solution is compared to the concentration distribution in microcrystals of insoluble insertion compounds. (C) 1999 Elsevier Science S.A. All rights reserved.
引用
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页码:207 / 212
页数:6
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