A reduced polyoxomolybdenum borophosphate anion related to the Wells-Dawson clusters

被引：49

作者：

Dumas, E

Debiemme-Chouvy, C

Sevov, SC ^{[1
]}

机构：

[1] Univ Notre Dame, Dept Chem & Biochem, Notre Dame, IN 46556 USA

[2] Univ Versailles, Inst Lavoisier, F-78035 Versailles, France

来源：

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY | 2002年 / 124卷 / 06期

关键词：

D O I：

10.1021/ja012352r

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The new compound (C3N2H5)8[MoV 5MoVI 7O22(BO4)2(PO4)5(HPO4)3]·nH2O is the first molybdenum borophosphate. It contains clusters of twelve molybdenum, eight phosphorus and two boron atoms, [Mo12O22(BO4)2(PO4)5(HPO4)3]8- similar to the Wells-Dawson clusters. Five molybdenum atoms are MoV while the others are MoVI, and the five electrons are delocalized. According to the temperature dependence of the magnetic susceptibility four of these electrons are paired. Copyright © 2002 American Chemical Society.

引用

页码：908 / 909

页数：2

共 36 条

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