Carbon dioxide activation: Synthesis and characterization of a cadmium(II) dinuclear complex with a novel mu-carbonato bridge

被引：11

作者：

Pariya, C ^{[1
]}

Puranik, VG ^{[1
]}

Chaudhuri, NR ^{[1
]}

机构：

[1] NATL CHEM LAB,DEPT PHYS CHEM,PUNE 411008,MAHARASHTRA,INDIA

来源：

CHEMICAL COMMUNICATIONS | 1997年 / 14期

关键词：

D O I：

10.1039/a701676j

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The cadmium(Ir) complex of N'-isopropyl-2-methylpropane-1,2-diamine (npda), [Cd(npda)(3)][ClO4](2) 1 in aqueous methanol absorbs CO2 from air to form a cadmium(II) dinuclear complex, [Cd(npda)(4)(CO3)(H2O)][ClO4](2) . H2O 2, the first ever example of a mu-carbonato cadmium(II) diamine complex which is characterized by elemental analysis, IR and crystal structure determination.

引用

页码：1307 / 1308

页数：2

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