Synthesis of cyclitols via ring-closing metathesis

被引：43

作者：

Kornienko, A ^{[1
]}

d'Alarcao, M ^{[1
]}

机构：

[1] Tufts Univ, Dept Chem, Medford, MA 02155 USA

来源：

TETRAHEDRON-ASYMMETRY | 1999年 / 10卷 / 05期

基金：

美国国家卫生研究院;

关键词：

D O I：

10.1016/S0957-4166(99)00065-8

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

A convenient synthesis of enantiomerically pure and differentially protected L-chiro- and myo-inositols as well as conduritols B and F from 2,3,4-tri-O-benzyl-D-xylopyranose via ring-closing metathesis is reported. The facile synthesis of conduritol B constitutes a short formal synthesis of (-)-cyclophellitol. (C) 1999 Elsevier Science Ltd. All rights reserved.

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收藏

页码：827 / 829

页数：3

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