Strong, tough, electrospun polymer-nanotube composite membranes with extremely low density

被引：57

作者：

Blond, David ^{[1
]}

Walshe, William ^{[1
]}

Young, Karen ^{[1
]}

Blighe, Fiona M. ^{[1
]}

Khan, Umar ^{[1
]}

Almecija, Dorothee ^{[2
,3
]}

Carpenter, Leslie ^{[1
,4
]}

McCauley, Joe ^{[1
]}

Blau, Werner J. ^{[1
]}

Coleman, Jonathan N. ^{[1
]}

机构：

[1] Trinity Coll Dublin, Sch Phys, Dublin 2, Ireland

[2] Trinity Coll Dublin, Sch Chem, Dublin 2, Ireland

[3] Trinity Coll Dublin, Ctr Res Adapt Nanostruct & Nanodevices, Dublin 2, Ireland

[4] Dow Corning Corp, Midland, MI 48640 USA

来源：

ADVANCED FUNCTIONAL MATERIALS | 2008年 / 18卷 / 17期

基金：

爱尔兰科学基金会;

关键词：

D O I：

10.1002/adfm.200701487

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Electrospinning has been used to produce porous, low density, polymer-nanotube composite membranes. The membrane mechanical properties can be enhanced by tuning the nanotube content, aligning the fibers during spinning, and by post production drawing. The mechanical properties are maximized for membranes with a nanotube content of 0.43 vol %. Aligned composites at this volume fraction have been prepared by spinning onto a rotating drum collector electrode. This method results, produced at the maximum drum rotation rate, in significant increases in modulus, strength, and toughness. The best composites. were post treated by a drawing step to result in further increases in modulus and strength. These methods allows the production of membranes with densities as low as similar to 340kg m(-3) but with values of stiffness, strengths and tougghness's more typically found in bulk thermoplastics; 1.2 GPa, 40 MPa, and 13 J g(-1).

引用

页码：2618 / 2624

页数：7

共 27 条

[1] High quality dispersions of functionalized single walled nanotubes at high concentration [J].