STM of mixed alkylthiol self-assembled monolayers on Au(111)

被引：21

作者：

Klein, H ^{[1
]}

Battaglini, N ^{[1
]}

Bellini, B ^{[1
]}

Dumas, P ^{[1
]}

机构：

[1] Fac Sci Luminy, GPEC, UMR CNRS 6631, F-13288 Marseille 9, France

来源：

MATERIALS SCIENCE & ENGINEERING C-BIOMIMETIC AND SUPRAMOLECULAR SYSTEMS | 2002年 / 19卷 / 1-2期

关键词：

alkylthiol; self-assembled monolayers; scanning tunnelling microscopy;

D O I：

10.1016/S0928-4931(01)00399-X

中图分类号：

T [工业技术];

学科分类号：

08 ;

摘要：

Mixed self-assembled monolayers (SAMs) consisting of n-alkylthiol and/or 11-mercaptol-undecanol are produced and investigated by Scanning Tunnelling Microscopy (STM) in picoampere regime. Such systems allow the creation of surfaces with tuned chemical properties. We investigate both the qualities of the organic films and their electron transport properties. We evidence a contact regime and measure the decay lengths both in the film and in the tunnelling gap. (C) 2002 Published by Elsevier Science B.V.

引用

页码：279 / 283

页数：5

共 28 条

[1] DOMAIN AND MOLECULAR SUPERLATTICE STRUCTURE OF DODECANETHIOL SELF-ASSEMBLED ON AU(111) [J].

ANSELMETTI, D ;

BARATOFF, A ;

GUNTHERODT, HJ ;

DELAMARCHE, E ;

MICHEL, B ;

GERBER, C ;

KANG, H ;

WOLF, H ;

RINGSDORF, H .

EUROPHYSICS LETTERS, 1994, 27 (05) :365-370

[2] Molecular packing changes of alkanethiols monolayers on Au(111) under applied pressure [J].

Barrena, E ;

Ocal, C ;

Salmeron, M .

JOURNAL OF CHEMICAL PHYSICS, 2000, 113 (06) :2413-2418

[3] Electron transfer through organic molecules [J].

Bumm, LA ;

Arnold, JJ ;

Dunbar, TD ;

Allara, DL ;

Weiss, PS .

JOURNAL OF PHYSICAL CHEMISTRY B, 1999, 103 (38) :8122-8127

[4] SUPERLATTICE STRUCTURE AT THE SURFACE OF A MONOLAYER OF OCTADECANETHIOL SELF-ASSEMBLED ON AU(111) [J].

CAMILLONE, N ;

CHIDSEY, CED ;

LIU, GY ;

SCOLES, G .

JOURNAL OF CHEMICAL PHYSICS, 1993, 98 (04) :3503-3511

[5] Placement of conjugated oligomers in an alkanethiol matrix by scanned probe microscope lithography [J].

Chen, J ;

Reed, MA ;

Asplund, CL ;

Cassell, AM ;

Myrick, ML ;

Rawlett, AM ;

Tour, JM ;

Van Patten, PG .

APPLIED PHYSICS LETTERS, 1999, 75 (05) :624-626

[6] High-resolution imaging of the self-assembly of organic monolayers [J].

Chiang, S .

SCIENCE, 1996, 272 (5265) :1123-1124

[7] Insertion, conductivity, and structures of conjugated organic oligomers in self-assembled alkanethiol monolayers on Au{111} [J].

Cygan, MT ;

Dunbar, TD ;

Arnold, JJ ;

Bumm, LA ;

Shedlock, NF ;

Burgin, TP ;

Jones, L ;

Allara, DL ;

Tour, JM ;

Weiss, PS .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1998, 120 (12) :2721-2732

[8]

FOKKINK LGJ, 1994, LANGMUIR, V10, P611

[9] SELF-ASSEMBLED MONOLAYERS OF ALKANETHIOLS ON GOLD - COMPARISONS OF MONOLAYERS CONTAINING MIXTURES OF SHORT-CHAIN AND LONG-CHAIN CONSTITUENTS WITH CH3 AND CH2OH TERMINAL GROUPS [J].

FOLKERS, JP ;

LAIBINIS, PE ;

WHITESIDES, GM .

LANGMUIR, 1992, 8 (05) :1330-1341

[10] Structural effects on electrical conduction of conjugated molecules studied by scanning tunneling microscopy [J].

Ishida, T ;

Mizutani, W ;

Choi, N ;

Akiba, U ;

Fujihira, M ;

Tokumoto, H .

JOURNAL OF PHYSICAL CHEMISTRY B, 2000, 104 (49) :11680-11688

← 1 2 3 →